化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2015年
5期
1427-1432
,共6页
全红平%吴洋%黄志宇%张太亮
全紅平%吳洋%黃誌宇%張太亮
전홍평%오양%황지우%장태량
降滤失剂%阴离子聚合物%抗高温%抗盐%抗钙
降濾失劑%陰離子聚閤物%抗高溫%抗鹽%抗鈣
강려실제%음리자취합물%항고온%항염%항개
fluid loss additives%anionic polymer%temperature resistant%salt tolerance%calcium resistance
选用对苯乙烯磺酸钠(SSS)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)、丙烯酰胺(AM)单体为原料,利用自由基聚合的方式,得到一种抗高温耐盐聚合物降滤失剂。通过傅里叶红外光谱分析(FT-IR)表明合成产物结构与设计结构相符。当降滤失剂加量为1.8%时,室温下和210℃下淡水基浆的滤失量分别为7.9mL和13.5mL;在25%NaCl和3%CaCl2的盐水泥浆中,钻井液的滤失量分别为14.8mL和11.0mL。通过扫描电镜(SEM)可以分析钻井液形成的滤饼的微观结构,由此得到降滤失剂作用的机理是:当降滤失剂吸附在黏土表面时,降滤失剂可以使黏土颗粒在钻井液中分散,从而形成致密的滤饼来减少滤失量。
選用對苯乙烯磺痠鈉(SSS)、2-丙烯酰胺基-2-甲基丙磺痠(AMPS)、丙烯酰胺(AM)單體為原料,利用自由基聚閤的方式,得到一種抗高溫耐鹽聚閤物降濾失劑。通過傅裏葉紅外光譜分析(FT-IR)錶明閤成產物結構與設計結構相符。噹降濾失劑加量為1.8%時,室溫下和210℃下淡水基漿的濾失量分彆為7.9mL和13.5mL;在25%NaCl和3%CaCl2的鹽水泥漿中,鑽井液的濾失量分彆為14.8mL和11.0mL。通過掃描電鏡(SEM)可以分析鑽井液形成的濾餅的微觀結構,由此得到降濾失劑作用的機理是:噹降濾失劑吸附在黏土錶麵時,降濾失劑可以使黏土顆粒在鑽井液中分散,從而形成緻密的濾餅來減少濾失量。
선용대분을희광산납(SSS)、2-병희선알기-2-갑기병광산(AMPS)、병희선알(AM)단체위원료,이용자유기취합적방식,득도일충항고온내염취합물강려실제。통과부리협홍외광보분석(FT-IR)표명합성산물결구여설계결구상부。당강려실제가량위1.8%시,실온하화210℃하담수기장적려실량분별위7.9mL화13.5mL;재25%NaCl화3%CaCl2적염수니장중,찬정액적려실량분별위14.8mL화11.0mL。통과소묘전경(SEM)가이분석찬정액형성적려병적미관결구,유차득도강려실제작용적궤리시:당강려실제흡부재점토표면시,강려실제가이사점토과립재찬정액중분산,종이형성치밀적려병래감소려실량。
A ternary copolymer of 2-acrylamide-2-methyl propane sulfonic acid (AMPS),acrylamide (AM) and sodium styrene sulfonate (SSS) was designed and synthesized by free radical polymerization as fluid loss additive for drilling fluid at high temperature and high salt content. The chemical structure of the copolymer was characterized by Fourier transform infrared spectrum (FT-IR). When 1.8% fluid loss additive was added into the freshwater based mud,filtration of drilling fluid was 7.9 mL at room temperature and 13.5 mL at 210℃. In the presence of NaCl of concentration 25% and CaCl2 of concentration 3% as salt water mud,the filtration values of drilling fluid were 14.8 mL and 11.0 mL, respectively. Scanning electron microscopy (SEM) analysis showed the microstructure of the surface of the filter cake obtained from the drilling fluid. When fluid loss additive was adsorbed on the surface of clay particles,clay particles were dispersed in the drilling fluid to form steady dispersion system. The filter cake would be uniform and fluid loss was reduced.