中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2015年
4期
990-996
,共7页
周文艳%易茂中%冉丽萍%彭可%葛毅成
週文豔%易茂中%冉麗萍%彭可%葛毅成
주문염%역무중%염려평%팽가%갈의성
Mo2C涂层%C/C-Cu复合材料%熔渗%摩擦性能
Mo2C塗層%C/C-Cu複閤材料%鎔滲%摩抆性能
Mo2C도층%C/C-Cu복합재료%용삼%마찰성능
Mo2C interlayer%C/C-Cu composite%infiltration%tribological property
以仲钼酸铵为反应物,采用熔盐法在低密度C/C复合材料孔隙表面制备Mo2C涂层,改善Cu与C/C坯体的润湿性,然后通过无压熔渗Cu制备C/C-Cu复合材料,研究了Mo2C改性层制备温度对Mo2C涂层和C/C-Cu复合材料组织结构及性能的影响。结果表明:Mo2C涂层在坯体内部孔隙表面分布均匀,且与炭基体和Cu均有良好的界面结合。在950~1150℃范围内,随涂层反应温度的提高,Mo2C层厚度由2.0μm逐渐增大到6.5μm,C/C-Cu复合材料的密度逐渐增大,电阻率逐渐降低;抗弯强度呈现先增大后减小趋势,在涂层反应温度为1000℃时呈现最大值251.83 MPa。复合材料的摩擦因数均随磨损时间延长先增大后减小并趋于稳定。随着Mo2C涂层制备温度的提高,复合材料的摩擦因数逐渐增大,体积磨损率先减小后增加,在Mo2C涂层反应温度为1000℃时,复合材料的磨损率最低。
以仲鉬痠銨為反應物,採用鎔鹽法在低密度C/C複閤材料孔隙錶麵製備Mo2C塗層,改善Cu與C/C坯體的潤濕性,然後通過無壓鎔滲Cu製備C/C-Cu複閤材料,研究瞭Mo2C改性層製備溫度對Mo2C塗層和C/C-Cu複閤材料組織結構及性能的影響。結果錶明:Mo2C塗層在坯體內部孔隙錶麵分佈均勻,且與炭基體和Cu均有良好的界麵結閤。在950~1150℃範圍內,隨塗層反應溫度的提高,Mo2C層厚度由2.0μm逐漸增大到6.5μm,C/C-Cu複閤材料的密度逐漸增大,電阻率逐漸降低;抗彎彊度呈現先增大後減小趨勢,在塗層反應溫度為1000℃時呈現最大值251.83 MPa。複閤材料的摩抆因數均隨磨損時間延長先增大後減小併趨于穩定。隨著Mo2C塗層製備溫度的提高,複閤材料的摩抆因數逐漸增大,體積磨損率先減小後增加,在Mo2C塗層反應溫度為1000℃時,複閤材料的磨損率最低。
이중목산안위반응물,채용용염법재저밀도C/C복합재료공극표면제비Mo2C도층,개선Cu여C/C배체적윤습성,연후통과무압용삼Cu제비C/C-Cu복합재료,연구료Mo2C개성층제비온도대Mo2C도층화C/C-Cu복합재료조직결구급성능적영향。결과표명:Mo2C도층재배체내부공극표면분포균균,차여탄기체화Cu균유량호적계면결합。재950~1150℃범위내,수도층반응온도적제고,Mo2C층후도유2.0μm축점증대도6.5μm,C/C-Cu복합재료적밀도축점증대,전조솔축점강저;항만강도정현선증대후감소추세,재도층반응온도위1000℃시정현최대치251.83 MPa。복합재료적마찰인수균수마손시간연장선증대후감소병추우은정。수착Mo2C도층제비온도적제고,복합재료적마찰인수축점증대,체적마손솔선감소후증가,재Mo2C도층반응온도위1000℃시,복합재료적마손솔최저。
In order to improve the wetting ability between molten copper and C/C preform, Mo2C interlayer was fabricated on the internal surface of C/C preform via molten salt deposition using ammonium paramolybdate as reactant. Then, C/C-Cu composites were prepared by pressureless infiltration. The influences of preparation temperature of Mo2C interlayer on the microstructure and properties of Mo2C interlayer and C/C-Cu composite were investigated. The results show that the Mo2C interlayer covered internal pore surface of the C/C preform uniformly has a good interface bonding with C/C substrate and Cu. With the increase of preparation temperature in the range of 950?1150℃, the thickness of the Mo2C interlayer increases from 2.0 μm to 6.5 μm, the density of C/C-Cu composite increases, the electrical resistivity decreases, the flexural strength firstly increases and then decreases, and reaches the maximum value (251.83 MPa) at 1000 ℃. The friction coefficient of the C/C-Cu composite firstly increases and then decreases to a stable value with friction time increasing. With the increase of the reaction temperature, the friction coefficient increases, the volume abrasion rate firstly decreases and then increases, and reaches the minimum value at 1000℃.