CAJ | 학술논문

以甲基氢二氯硅烷、甲基乙烯基二氯硅烷为原料,采用氨解反应以及热聚合反应合成了一系列乙烯基氢基甲基聚硅氮烷(PSZ135-170),其数均分子量(Mn)在2．9×103~1．9×105之间,单位浓度聚合物的粘度(ηred)在0．06~0．49mL/g之间.通过FTIR和1HNMR对聚硅氮烷结构进行了表征,该系列聚硅氮烷具有无定型结构,可溶解于正己烷、甲苯、乙酸乙酯、二氯甲烷和N,N-二甲基甲酰胺等常用有机溶剂中,通过TGA分析了该系列聚硅氮烷的热性能,发现随着聚硅氮烷分子量的增加,在N2中25~700℃热解后剩余物的百分含量逐渐升高,最高可达72．58％.
이갑기경이록규완、갑기을희기이록규완위원료,채용안해반응이급열취합반응합성료일계렬을희기경기갑기취규담완(PSZ135-170),기수균분자량(Mn)재2．9×103~1．9×105지간,단위농도취합물적점도(ηred)재0．06~0．49mL/g지간.통과FTIR화1HNMR대취규담완결구진행료표정,해계렬취규담완구유무정형결구,가용해우정기완、갑분、을산을지、이록갑완화N,N-이갑기갑선알등상용유궤용제중,통과TGA분석료해계렬취규담완적열성능,발현수착취규담완분자량적증가,재N2중25~700℃열해후잉여물적백분함량축점승고,최고가체72．58％.
A series of Vinylhydromethylpolysilazanes(PSZ135-170)were prepared from dichlorohydromethylsi-lane and dichloromethylvinylsilane by ammonolysis polycondensation and thermopolymerization.The vinyl-hydromethyl polysilazanes have number-average molecular weights (Mn)of 2.9×103-1.9×105.The reduced viscosity (ηred)of the polymers are 0.06-0.49 mL/g.The structures of the polysilazanes were characterized by FT-IR and 1 H NMR.The polysilazanes are amorphous and soluble in common organic solvents such as hexane, toluene,ethyl acetate,dichloromethane,N,N-dimethylformamide and so on.The thermal properties of the pol-ysilazanes were analyzed by TGA.It was found that the residual percent of the series of the PSZ enhanced grad-ually after pyrolysis in nitrogen at 25-700 ℃ along with the increasing of molecular weights,could almost reach 72.58%.