重庆大学学报
重慶大學學報
중경대학학보
Journal of Chongqing University (Natural Science Edition)
2015年
2期
93-98
,共6页
薛正良%余晨帆%邱龙武%陈婉婷%张京
薛正良%餘晨帆%邱龍武%陳婉婷%張京
설정량%여신범%구룡무%진완정%장경
帘线钢%碳氮化钛夹杂%凝固析出%固溶
簾線鋼%碳氮化鈦夾雜%凝固析齣%固溶
렴선강%탄담화태협잡%응고석출%고용
tire cord steel%titanium carbonitride inclusions%precipitation during solidification%solid solution
应用热力学方法研究了帘线钢凝固析出碳氮化钛(Ti(C狓N1-狓))夹杂的性质,以及钢坯加热过程碳氮化钛(Ti(C狓N1-狓))夹杂分解固溶的热力学条件,并通过实验研究了试样高温加热过程中碳氮化钛夹杂的固溶现象。研究表明:1)帘线钢 C 含量越高,凝固析出的碳氮化钛夹杂中的狓值越高;2)帘线钢 C 含量越高,凝固过程碳氮化钛夹杂析出就越早,析出碳氮化钛夹杂时的凝固前沿温度越低;3)82A 铸坯加热到1087℃以上时,碳氮化钛夹杂具备分解和固溶的热力学条件;4)实验验证将钢样在1150℃和1250℃高温加热后,5μm 以上的碳氮化钛夹杂分别下降了55%和70.3%,而试样在1250℃高温加热后缓冷到1000℃时发现2μm 以下的小夹杂继续在分解,而5μm以上的大夹杂在增加。
應用熱力學方法研究瞭簾線鋼凝固析齣碳氮化鈦(Ti(C狓N1-狓))夾雜的性質,以及鋼坯加熱過程碳氮化鈦(Ti(C狓N1-狓))夾雜分解固溶的熱力學條件,併通過實驗研究瞭試樣高溫加熱過程中碳氮化鈦夾雜的固溶現象。研究錶明:1)簾線鋼 C 含量越高,凝固析齣的碳氮化鈦夾雜中的狓值越高;2)簾線鋼 C 含量越高,凝固過程碳氮化鈦夾雜析齣就越早,析齣碳氮化鈦夾雜時的凝固前沿溫度越低;3)82A 鑄坯加熱到1087℃以上時,碳氮化鈦夾雜具備分解和固溶的熱力學條件;4)實驗驗證將鋼樣在1150℃和1250℃高溫加熱後,5μm 以上的碳氮化鈦夾雜分彆下降瞭55%和70.3%,而試樣在1250℃高溫加熱後緩冷到1000℃時髮現2μm 以下的小夾雜繼續在分解,而5μm以上的大夾雜在增加。
응용열역학방법연구료렴선강응고석출탄담화태(Ti(C피N1-피))협잡적성질,이급강배가열과정탄담화태(Ti(C피N1-피))협잡분해고용적열역학조건,병통과실험연구료시양고온가열과정중탄담화태협잡적고용현상。연구표명:1)렴선강 C 함량월고,응고석출적탄담화태협잡중적피치월고;2)렴선강 C 함량월고,응고과정탄담화태협잡석출취월조,석출탄담화태협잡시적응고전연온도월저;3)82A 주배가열도1087℃이상시,탄담화태협잡구비분해화고용적열역학조건;4)실험험증장강양재1150℃화1250℃고온가열후,5μm 이상적탄담화태협잡분별하강료55%화70.3%,이시양재1250℃고온가열후완랭도1000℃시발현2μm 이하적소협잡계속재분해,이5μm이상적대협잡재증가。
The properties of titanium carbonitride (Ti(CxN1 -x))inclusions precipitated during solidification of tire cord steel,as well as thermodynamic conditions of decomposition and solid solution of titanium carbonitride (Ti (CxN1 -x ))inclusions in the billet heating process are studied by thermodynamics.The solid solution phenomenon of titanium carbonitride inclusions in the high temperature heating process is studied with lab experiment.The results show 1 )The higher the carbon content in tire cord steel,the higher the value of x in titanium carbonitride inclusions;2 )The higher the carbon content in tire cord steel,the earlier the titanium carbonitride inclusions precipitated during solidification process,the lower solidfication front temperature of precipitation of titanium carbonitride inclusions.3 ) When heated to 1 087 ℃,the titanium carbonitride inclusions of 82A billet possess the thermodynamic conditions of decomposition and solid solution;4 )When heated to 1 150 ℃ and 1 250 ℃,the content of titanium carbonitride inclusions with size more than 5 μm are decreased by 55% and 70.3% respectively;However the small inclusions with size less than 2 μm continue to decompose,and the content of inclusions with size more than 5 μm increases when the sample is heating at 1 250 ℃ for two hours then furnace cooling to 1 000 ℃.