腐蚀与防护
腐蝕與防護
부식여방호
CORROSION & PROTECTION
2015年
4期
378-380,385
,共4页
杨俊%郭俊文%柯于进%邓宇强%韩霜%李瑛
楊俊%郭俊文%柯于進%鄧宇彊%韓霜%李瑛
양준%곽준문%가우진%산우강%한상%리영
内冷水%铜导线%二氧化碳%氢电导率(CC)%腐蚀
內冷水%銅導線%二氧化碳%氫電導率(CC)%腐蝕
내랭수%동도선%이양화탄%경전도솔(CC)%부식
inner cooling water%copper conductor%carbon dioxide%cation conductivity (CC)%corrosion
发电机内冷水系统中由于二氧化碳的溶入并不断累积产生的问题日渐突出。通过理论分析了二氧化碳与氢电导率及 pH 的关系,利用动态模拟试验台,采用电化学方法研究了不同二氧化碳量对发电机内冷水铜导线腐蚀的影响。提出用氢电导率对二氧化碳含量进行表征,在监测内冷水水质时,对氢电导率进行监测,控制氢电导率在0.1μS/cm 以下,以提高对铜的缓蚀保护效果和内冷水 pH 在线测量的准确性。
髮電機內冷水繫統中由于二氧化碳的溶入併不斷纍積產生的問題日漸突齣。通過理論分析瞭二氧化碳與氫電導率及 pH 的關繫,利用動態模擬試驗檯,採用電化學方法研究瞭不同二氧化碳量對髮電機內冷水銅導線腐蝕的影響。提齣用氫電導率對二氧化碳含量進行錶徵,在鑑測內冷水水質時,對氫電導率進行鑑測,控製氫電導率在0.1μS/cm 以下,以提高對銅的緩蝕保護效果和內冷水 pH 在線測量的準確性。
발전궤내랭수계통중유우이양화탄적용입병불단루적산생적문제일점돌출。통과이론분석료이양화탄여경전도솔급 pH 적관계,이용동태모의시험태,채용전화학방법연구료불동이양화탄량대발전궤내랭수동도선부식적영향。제출용경전도솔대이양화탄함량진행표정,재감측내랭수수질시,대경전도솔진행감측,공제경전도솔재0.1μS/cm 이하,이제고대동적완식보호효과화내랭수 pH 재선측량적준학성。
At present,the problem of carbon dioxide dissolation and continuous accumulation in the generator inner cooling water is increasingly outstanding.The relationships of cation conductivity (CC)and pH with carbon dioxide was theoretically analyzed.And the influence of carbon dioxide at different degree contents on the corrosion of copper conductor in the generator inner cooling water was studied by electrochemical method and using a dynamic simulation experiment set.The results showed that it was appropriate to utilize the cation conductivity to represent the content of dissolved carbon dioxide and to supervise and control the cation conductivity below 0.1 μS/cm when inner cooling water was supervised so as to improve the corrosion protection effect of copper and veracity of on-line measurement of pH.