生态环境学报
生態環境學報
생태배경학보
ECOLOGY AND ENVIRONMENT
2015年
3期
529-532
,共4页
孙翠香%王首君%毕鸿亮%高原雪%蔡洋
孫翠香%王首君%畢鴻亮%高原雪%蔡洋
손취향%왕수군%필홍량%고원설%채양
3,3′-二氯联苯胺%气相色谱/质谱%土壤
3,3′-二氯聯苯胺%氣相色譜/質譜%土壤
3,3′-이록련분알%기상색보/질보%토양
3,3′-Dichlorobenzidine%Gas chromatography/mass spectrometry%soil
建立了气相色谱/质谱来测定土壤中芳香胺3,3′-二氯联苯胺的方法。该化合物通过超声波辅助萃取，选择正己烷-丙酮混合溶剂（体积比为1∶1）或乙酸乙酯，以及Cleanert S C18-SPE柱进行净化。该方法测定土壤中3,3’-二氯联苯胺的检出限为2.8μg·kg-1（信噪比S/N=3）；3,3′-二氯联苯胺的加标回收率平均值为89.7%（n=5）；重复进样RSD为3.55%（n=5）。该方法的线性范围是120~2400μg·kg-1，相关系数0.9995。该方法也可用于沉积物中3,3′-二氯联苯胺的测定。
建立瞭氣相色譜/質譜來測定土壤中芳香胺3,3′-二氯聯苯胺的方法。該化閤物通過超聲波輔助萃取，選擇正己烷-丙酮混閤溶劑（體積比為1∶1）或乙痠乙酯，以及Cleanert S C18-SPE柱進行淨化。該方法測定土壤中3,3’-二氯聯苯胺的檢齣限為2.8μg·kg-1（信譟比S/N=3）；3,3′-二氯聯苯胺的加標迴收率平均值為89.7%（n=5）；重複進樣RSD為3.55%（n=5）。該方法的線性範圍是120~2400μg·kg-1，相關繫數0.9995。該方法也可用于沉積物中3,3′-二氯聯苯胺的測定。
건립료기상색보/질보래측정토양중방향알3,3′-이록련분알적방법。해화합물통과초성파보조췌취，선택정기완-병동혼합용제（체적비위1∶1）혹을산을지，이급Cleanert S C18-SPE주진행정화。해방법측정토양중3,3’-이록련분알적검출한위2.8μg·kg-1（신조비S/N=3）；3,3′-이록련분알적가표회수솔평균치위89.7%（n=5）；중복진양RSD위3.55%（n=5）。해방법적선성범위시120~2400μg·kg-1，상관계수0.9995。해방법야가용우침적물중3,3′-이록련분알적측정。
This study developed the determination of 3,3′-Dichlorobenzidine in soil sample by gas chromatography- Mass spectrometry. The compounds were extracted from soil by sonication assisted extraction with volume of the mixture of acetone and hexane (V?V=1?1) or ethylacetate as extraction solvent; an Cleanert S C18-SPE was carried out to remove interferences. Average recoveries from spiked samples were 89.7% (n=5) and the estimated limits of detection varied 2.8 μg·kg-1 (S/N=3). The repeatability (RSD) equals 3.55%. The response obtained with this method was linear over the range assayed, 120~2400 μg·kg-1 with correlation coefficient of 0.9995. The validated method can also be used to investigate 3,3′-Dichlorobenzidine in Sediment Matrices samples.
