电镀与涂饰
電鍍與塗飾
전도여도식
ELECTROPLATING & FINISHING
2015年
5期
251-256
,共6页
陆永亮%王洺浩%曹美霞%陆伟星%王志登%李宁
陸永亮%王洺浩%曹美霞%陸偉星%王誌登%李寧
륙영량%왕명호%조미하%륙위성%왕지등%리저
甲磺酸盐镀锡%钝化%耐蚀性%铬含量%漆膜结合力
甲磺痠鹽鍍錫%鈍化%耐蝕性%鉻含量%漆膜結閤力
갑광산염도석%둔화%내식성%락함량%칠막결합력
mesylate tinplating%passivation%corrosion resistance%chrome content%coating adhesion
通过正交试验,研究了钝化电量、主盐浓度、钝化液pH与温度对甲磺酸盐镀锡板表面钝化膜铬含量、耐蚀性与漆膜结合力的影响。在本实验选定的参数范围内,钝化电量对以上3种性能都有较为显著的影响,尤其是漆膜结合力。钝化液pH对钝化膜的铬含量与耐蚀性影响最大,在实际生产中,钝化液的pH控制在4.2左右为最佳。生产高钝化电量镀锡板时,应避免采用过大的电流而影响钝化效果,并适当调低钢带走速作为配合。
通過正交試驗,研究瞭鈍化電量、主鹽濃度、鈍化液pH與溫度對甲磺痠鹽鍍錫闆錶麵鈍化膜鉻含量、耐蝕性與漆膜結閤力的影響。在本實驗選定的參數範圍內,鈍化電量對以上3種性能都有較為顯著的影響,尤其是漆膜結閤力。鈍化液pH對鈍化膜的鉻含量與耐蝕性影響最大,在實際生產中,鈍化液的pH控製在4.2左右為最佳。生產高鈍化電量鍍錫闆時,應避免採用過大的電流而影響鈍化效果,併適噹調低鋼帶走速作為配閤。
통과정교시험,연구료둔화전량、주염농도、둔화액pH여온도대갑광산염도석판표면둔화막락함량、내식성여칠막결합력적영향。재본실험선정적삼수범위내,둔화전량대이상3충성능도유교위현저적영향,우기시칠막결합력。둔화액pH대둔화막적락함량여내식성영향최대,재실제생산중,둔화액적pH공제재4.2좌우위최가。생산고둔화전량도석판시,응피면채용과대적전류이영향둔화효과,병괄당조저강대주속작위배합。
The effects of the quantity of charge passed during passivation as well as the main salt concentration, pH, and temperature of passivation bath on chrome content and corrosion resistance of passivation film on surface of mesylate tinplate and on its adhesion to subsequent coating were studied. It was found that in range of the selected parameters, the quantity of charge has a remarkable effect on the properties especially coating adhesion of passivation film. The pH of passivation bath has the greatest influence on chrome content and corrosion resistance of passivation film. In practical production, the pH of passivation bath should be controlled at about 4.2. When passivating tinplate with high quantity of charge, the speed of steel strip movement should be appropriately reduced accordingly and the use of excessive current be avoided.