火炸药学报
火炸藥學報
화작약학보
CHINESE JOURNAL OF EXPLOSIVES & PROPELLANTS
2015年
2期
8-14
,共7页
杨燕京%赵凤起%仪建华%罗阳
楊燕京%趙鳳起%儀建華%囉暘
양연경%조봉기%의건화%라양
固体推进剂%储氢材料%推进剂燃烧%金属氢化物%金属配位氢化物%金属氮氢化合物%氨硼烷
固體推進劑%儲氫材料%推進劑燃燒%金屬氫化物%金屬配位氫化物%金屬氮氫化閤物%氨硼烷
고체추진제%저경재료%추진제연소%금속경화물%금속배위경화물%금속담경화합물%안붕완
solid propellant%hydrogen-storage materials%propellant combustion%metal hydrides%metal complex hydrides%metal amides/imides%ammonia borane
系统介绍了金属氢化物、金属配位氢化物、金属氮氢化合物以及氨硼烷等储氢材料,在此基础上总结了储氢合金、轻金属氢化物和金属硼氢化合物在高能固体火箭推进剂领域的应用研究进展,指出上述储氢材料能够促进推进剂组分的分解,改善推进剂的燃烧性能并提高推进剂的能量性能;同时分析了各类储氢材料在高能固体推进剂中的应用前景和制约因素,提出金属氢化物和金属配位氢化物是可能应用于高能固体火箭推进剂的储氢材料;同时,需重点关注储氢材料对氧气和水的高敏感性以及与推进剂的相容性差等可能的制约因素。附参考文献37篇。
繫統介紹瞭金屬氫化物、金屬配位氫化物、金屬氮氫化閤物以及氨硼烷等儲氫材料,在此基礎上總結瞭儲氫閤金、輕金屬氫化物和金屬硼氫化閤物在高能固體火箭推進劑領域的應用研究進展,指齣上述儲氫材料能夠促進推進劑組分的分解,改善推進劑的燃燒性能併提高推進劑的能量性能;同時分析瞭各類儲氫材料在高能固體推進劑中的應用前景和製約因素,提齣金屬氫化物和金屬配位氫化物是可能應用于高能固體火箭推進劑的儲氫材料;同時,需重點關註儲氫材料對氧氣和水的高敏感性以及與推進劑的相容性差等可能的製約因素。附參攷文獻37篇。
계통개소료금속경화물、금속배위경화물、금속담경화합물이급안붕완등저경재료,재차기출상총결료저경합금、경금속경화물화금속붕경화합물재고능고체화전추진제영역적응용연구진전,지출상술저경재료능구촉진추진제조분적분해,개선추진제적연소성능병제고추진제적능량성능;동시분석료각류저경재료재고능고체추진제중적응용전경화제약인소,제출금속경화물화금속배위경화물시가능응용우고능고체화전추진제적저경재료;동시,수중점관주저경재료대양기화수적고민감성이급여추진제적상용성차등가능적제약인소。부삼고문헌37편。
The hydrogen-storage materials including the metal hydrides,metal complex hydrides,metal amides/imides and ammonia borane,were systematically introduced.Based on this,the research progress on the utilization of hydrogen-storage alloys,light metal hydrides and metal borohydrides in high-energy solid rocket propellants was summerized.It is pointed out that the above-metioned hydrogen-storage materials can promote the decomposition of components of propellants,improve its combustion properties and enhance its energy performances.Moreover,the prospects and limitations of applications of all kinds hydrogen-storage materials in high-energy solid rocket propellants were analyzed.It is proposed that metal hydrides and metal complex hydrides are promising candidates as additives in high-energy solid rocket propellant.Much attention should be paid to the possible limitations that hamper the utilization of hydrogen-storage materials in propellants,such as the high sensitivity of hydrogen-storage materials to oxygen and moisture and their potentially poor compatibility with the present propellants,with 37 references.