CAJ | 학술논문

以2，6，8，12-四乙酰基-2，4，6，8，10，12-六氮杂四环-[5，5，0，03，11，05，9]十二烷（TAIW）为原料，采用 N2 O5／HNO3为硝化剂硝解 TAIW 制备六硝基六氮杂异伍皍烷（CL-20）。通过系统研究 N2 O5／HNO3硝解 TAIW 的加料方式、温度、料比、反应时间、稀释用水量等因素对反应收率和纯度的影响，找出了最佳反应条件：反应温度60～80℃，反应时间7 h，m（TAIW）∶m （N2 O5）∶V（HNO3）＝3 g∶4 g∶15 mL，后处理时稀释用水量20 mL，CL-20收率为82．34％，纯度为98．29％。当以质量分数10％的 CF3 SO3 H／树脂为催化剂时，收率提高至87．35％，纯度基本不变，且催化剂的回收率达到99．15％。该方法避免硫酸的使用，减轻了废酸污染，具有较强的工业化应用前景。
이2，6，8，12-사을선기-2，4，6，8，10，12-륙담잡사배-[5，5，0，03，11，05，9]십이완（TAIW）위원료，채용 N2 O5／HNO3위초화제초해 TAIW 제비륙초기륙담잡이오즉완（CL-20）。통과계통연구 N2 O5／HNO3초해 TAIW 적가료방식、온도、료비、반응시간、희석용수량등인소대반응수솔화순도적영향，조출료최가반응조건：반응온도60～80℃，반응시간7 h，m（TAIW）∶m （N2 O5）∶V（HNO3）＝3 g∶4 g∶15 mL，후처리시희석용수량20 mL，CL-20수솔위82．34％，순도위98．29％。당이질량분수10％적 CF3 SO3 H／수지위최화제시，수솔제고지87．35％，순도기본불변，차최화제적회수솔체도99．15％。해방법피면류산적사용，감경료폐산오염，구유교강적공업화응용전경。
2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20)was prepared via nitrolysis of 2,6,8,12-tetraacetyl-2,4,6,8,10,12-hexaazatetracyclo [5,5,0,03 ,11 05 ,9 ]dodecane (TAIW)as starting material and N2 O5/HNO3 as nitrating agent.Through studying the effect of the reaction conditions such as filling type for nitrolysis of TAIW with N2 O5/ HNO3 ,temperature,the amount of HNO3 and N2 O5 ,reaction time,the amount of the diluted water on the yield and purity of CL-20,the optimal reaction conditions are determined as:reaction temperature 60-80 ℃,reaction time 7 h,the ratio of m(TAIW)∶m(N2 O5 )∶V (HNO3 )of 3 g∶4 g∶15 mL,and addition of diluted water in the post process 20 mL,at this time,the yield of CL-20 is 82.34% ,and its purity is 98.29%.When 10%CF3 SO3 H/resin is used as catalyst,the yield is up to 87.35% ,its purity remains basically unchanged and the recovery rate of catalyst reaches to 99.15%.This method can avoid the use of sulfuric acid and reduce the pollution of the waste acid with strong industrial application prospect.