东北电力大学学报
東北電力大學學報
동북전력대학학보
JOURNAL OF NORTHEAST DIANLI UNIVERSITY
2015年
2期
65-68
,共4页
徐小惠%关晓辉%王秋阳%张兰河%鲁敏
徐小惠%關曉輝%王鞦暘%張蘭河%魯敏
서소혜%관효휘%왕추양%장란하%로민
酸化%铁/碳内电解%ABR%油页岩干馏废水
痠化%鐵/碳內電解%ABR%油頁巖榦餾廢水
산화%철/탄내전해%ABR%유혈암간류폐수
Acidification%Ferric-carbon micro-electrolysis%ABR%Oil shale retort wastewater
采用酸化-铁/碳内电解-ABR(厌氧折流板反应器)处理油页岩干馏废水,考察了最佳酸化条件;铁/碳内电解工艺中的铁碳比、pH值及反应时间等影响因素;ABR工艺最佳处理条件。结果表明:酸化隔油处理最优条件是将油页岩干馏废水pH值调为4.0,静沉24 h;铁/碳内电解最优条件:铁/碳质量比为5∶8,pH值为5.0,反应时间为60 min,静沉2 h;采用ABR处理铁/碳内电解出水,进水CODcr<2000 mg/L,水力停留时间为48 h,使得挥发酚的总去除率达到100%,矿物油总去除率达到99.8%, CODcr的总去除率可达97%。出水CODcr达到污水综合排放标准(GB8978-1996)三级排放标准,说明该技术具有可行性。
採用痠化-鐵/碳內電解-ABR(厭氧摺流闆反應器)處理油頁巖榦餾廢水,攷察瞭最佳痠化條件;鐵/碳內電解工藝中的鐵碳比、pH值及反應時間等影響因素;ABR工藝最佳處理條件。結果錶明:痠化隔油處理最優條件是將油頁巖榦餾廢水pH值調為4.0,靜沉24 h;鐵/碳內電解最優條件:鐵/碳質量比為5∶8,pH值為5.0,反應時間為60 min,靜沉2 h;採用ABR處理鐵/碳內電解齣水,進水CODcr<2000 mg/L,水力停留時間為48 h,使得揮髮酚的總去除率達到100%,礦物油總去除率達到99.8%, CODcr的總去除率可達97%。齣水CODcr達到汙水綜閤排放標準(GB8978-1996)三級排放標準,說明該技術具有可行性。
채용산화-철/탄내전해-ABR(염양절류판반응기)처리유혈암간류폐수,고찰료최가산화조건;철/탄내전해공예중적철탄비、pH치급반응시간등영향인소;ABR공예최가처리조건。결과표명:산화격유처리최우조건시장유혈암간류폐수pH치조위4.0,정침24 h;철/탄내전해최우조건:철/탄질량비위5∶8,pH치위5.0,반응시간위60 min,정침2 h;채용ABR처리철/탄내전해출수,진수CODcr<2000 mg/L,수력정류시간위48 h,사득휘발분적총거제솔체도100%,광물유총거제솔체도99.8%, CODcr적총거제솔가체97%。출수CODcr체도오수종합배방표준(GB8978-1996)삼급배방표준,설명해기술구유가행성。
The combined process of acidification and ferric-carbon micro-electrolysis and Anaerobic baffled re-actor was used to pre-treat oil shale retort wastewater. The influence factors,such as optimum acidized condi-tion,ferrous-carbon ratio,pH value and reaction time were investigated;ABR process optimum processing con-ditions. The results showed:in the acidification process,the optimum oil shale retort wastewater acidized condi-tions were pH value 4. 0 and sediment 24h. In the ferric-carbon micro-electrolysis process,the treatment effect of ferric-carbon micro-electrolysis was the best with ferrous-carbon ratio 5 ∶ 8 , pH value 5 . 0 , reaction time 60min and sediment 2h. Processing the water from ferric-carbon micro-electrolysis in the ABR,the optimum conditions were CODcr<2000mg/L and HRT 48h,the removal rate of phenol was 100%,the removal rate of mineral oils was 99. 8%,the removal rate of CODcr was 97%. The CODcr fully reached the third grade stand-ard in Wastewater Integrated Discharge Standard(GB8978-1996). It showed that the processing technique was feasible.