CAJ | 학술논문

用基斯勒尔法研究了热处理前后(室温~520℃)相沥青的流变性质。结果表明：在不同温度和不同加热速率下，基斯勒尔流动度具有很好的重现性。未经热处理的中间相沥青的流动度在253~282℃之间随温度增加缓慢增加，在282~311℃随温度增加呈现指数增大，在282~498℃几乎不变。热处理的沥青的流动度也随温度增加呈现类似的S型的变化规律，其中指数增加段可以用阿伦尼乌斯公式计算其粘流活化能。沥青的甲苯不溶物含量随热处理时间增大从67.3%增大到88.7%，粘流活化能为203.6~294 kJ/mol。
용기사륵이법연구료열처리전후(실온~520℃)상력청적류변성질。결과표명：재불동온도화불동가열속솔하，기사륵이류동도구유흔호적중현성。미경열처리적중간상력청적류동도재253~282℃지간수온도증가완만증가，재282~311℃수온도증가정현지수증대，재282~498℃궤호불변。열처리적력청적류동도야수온도증가정현유사적S형적변화규률，기중지수증가단가이용아륜니오사공식계산기점류활화능。력청적갑분불용물함량수열처리시간증대종67.3%증대도88.7%，점류활화능위203.6~294 kJ/mol。
The Giseeler fluidity method was used to investigate the rheological properties of pitch with and without heat treatment from room temperature to 520 ℃. Results show that the fluidity has a good repeatability at different temperatures under different heat-ing rates. The fluidity of the raw pitch slowly increases from 253 to 282℃, then increases exponentially from 282 to 311℃ near the softening temperature, and finally remains unchanged from 311 to 498 ℃. This changing pattern of fluidity with temperature has also been found for heat-treated mesophase pitch and can be formulated by the Arrhenius equation, from which the viscous flow activation energy can be obtained. The toluene-insoluble fraction increases from 67. 3% to 88. 7% with heat-treatment time and the flow activa-tion energy of the treated mesophase pitch in the Newtonian fluid region at low temperature range is between 203. 6 and 294 kJ/mol.