CAJ | 학술논문

随着稳定同位素分析技术的逐步完善，碳稳定同位素被广泛应用于地球化学领域。高砷地下水砷的生物地球化学循环是目前环境化学研究热点之一。分析概括了碳稳定同位素应用于地下水领域的研究现状，介绍了地下水中有机碳和无机碳稳定同位素的前处理方法以及测试技术。在此基础上，选取了内蒙古河套平原具有代表性的高砷地下水进行氧化还原敏感组分、碳稳定同位素的测定与分析。结果表明，As分布极不均匀，其含量为1.24～387μg／L。地下水溶解性有机碳（DOC）含量相对较高，与溶解性无机碳（DIC）浓度基本呈正相关。δ13 CDIC相对δ13 CDOC较富集13 C；δ13 CDIC －δ13 CDOC与δ13 CDIC之间具有显著的正相关关系；表明δ13 CDIC值越贫化，δ13 CDIC －δ13 CDOC越小，地下水中来源于有机物氧化分解的无机碳越多，进一步说明有机碳的氧化分解在无机碳稳定同位素贫化过程中起主要作用。此外，δ13 CDIC －δ13 CDOC与As浓度呈一定的负相关关系；表明有机物的微生物降解对砷的富集具有明显的促进作用。微生物可利用的碳源增加，促进异养微生物的代谢，并消耗氧气，最终形成有利于地下水As富集的还原环境。
수착은정동위소분석기술적축보완선，탄은정동위소피엄범응용우지구화학영역。고신지하수신적생물지구화학순배시목전배경화학연구열점지일。분석개괄료탄은정동위소응용우지하수영역적연구현상，개소료지하수중유궤탄화무궤탄은정동위소적전처리방법이급측시기술。재차기출상，선취료내몽고하투평원구유대표성적고신지하수진행양화환원민감조분、탄은정동위소적측정여분석。결과표명，As분포겁불균균，기함량위1.24～387μg／L。지하수용해성유궤탄（DOC）함량상대교고，여용해성무궤탄（DIC）농도기본정정상관。δ13 CDIC상대δ13 CDOC교부집13 C；δ13 CDIC －δ13 CDOC여δ13 CDIC지간구유현저적정상관관계；표명δ13 CDIC치월빈화，δ13 CDIC －δ13 CDOC월소，지하수중래원우유궤물양화분해적무궤탄월다，진일보설명유궤탄적양화분해재무궤탄은정동위소빈화과정중기주요작용。차외，δ13 CDIC －δ13 CDOC여As농도정일정적부상관관계；표명유궤물적미생물강해대신적부집구유명현적촉진작용。미생물가이용적탄원증가，촉진이양미생물적대사，병소모양기，최종형성유리우지하수As부집적환원배경。
With improved technology for stable isotope analysis,stable carbon isotope has extensively been used in the field of geochemical study.Biogeochemical cycle of groundwater arsenic is one of the hot topics in envi-ronmental studies.This paper summarizes research status of stable carbon isotope in groundwater,and intro-duces pretreating methods and measuring technology of organic and inorganic carbon isotope.Representative groundwater samples with high As concentrations were collected from the Hetao basin,Inner Mongolia,and ana-lyzed for redox-sensitive components,stable carbon isotope in dissolved organic carbon (DOC )and dissolved inorganic carbon (DIC).Results indicate that As distribution is patchy with concentrations between 1.24 and 387 μg/L,and that DOC concentration is relatively high and positively correlated with DIC.In comparison with DOC,DIC is enriched in 13C.There is a positive correlation betweenδ13CDIC -δ13CDOC andδ13CDIC.It indicates that groundwater with lowδ13 CDIC and lowδ13 CDIC -δ13 CDOC values has high contribution of DOC to DIC,which suggests that degradation of organic carbon results in depletion of 13 C in DIC of groundwater.In addition,there is a negative correlation between δ13 CDIC -δ13 CDOC and As.In groundwater with low δ13 CDIC and low δ13 CDIC -δ13 CDOC values,high As concentrations are observed.High As groundwater experiences intensive biodegradation of organic carbon,and microbial degradation of organic matters plays a significant role in promoting the enrich-ment of As in groundwater.The increase in bioavailable organic carbon promotes microbial dissimilation,con-sumes dissolved oxygen,and leads to formation of reducing conditions favorable for As enrichment in groundwater.