物理化学学报
物理化學學報
물이화학학보
ACTA PHYSICO-CHIMICA SINICA
2015年
4期
627-635
,共9页
梁初%梁升%夏阳%黄辉%甘永平%陶新永%张文魁
樑初%樑升%夏暘%黃輝%甘永平%陶新永%張文魁
량초%량승%하양%황휘%감영평%도신영%장문괴
氨基物%氢化物%储氢性能%热力学%动力学%储氢机理
氨基物%氫化物%儲氫性能%熱力學%動力學%儲氫機理
안기물%경화물%저경성능%열역학%동역학%저경궤리
Amide%Hydride%Hydrogen storage property%Thermodynamics%Kinetics%Hydrogen storage mechanism
Mg(NH2)2-2LiH材料是近年来发展起来的几种最具应用潜力的高容量储氢材料之一。由于具有较合适的吸放氢热力学性能、相对较低的吸放氢操作温度、较高的可逆储氢容量和较优的吸放氢循环稳定性, Mg(NH2)2-2LiH材料现已成为储氢材料研究领域的一个热点。本文综述了Mg(NH2)2-2LiH材料近年来的研究进展,重点关注了材料的组分、晶体结构、颗(晶)粒尺寸和催化动力学改性等对材料储氢性能的影响及储氢机理,总结了Mg(NH2)2-2LiH储氢材料存在的技术问题并指出了今后的研究方向。
Mg(NH2)2-2LiH材料是近年來髮展起來的幾種最具應用潛力的高容量儲氫材料之一。由于具有較閤適的吸放氫熱力學性能、相對較低的吸放氫操作溫度、較高的可逆儲氫容量和較優的吸放氫循環穩定性, Mg(NH2)2-2LiH材料現已成為儲氫材料研究領域的一箇熱點。本文綜述瞭Mg(NH2)2-2LiH材料近年來的研究進展,重點關註瞭材料的組分、晶體結構、顆(晶)粒呎吋和催化動力學改性等對材料儲氫性能的影響及儲氫機理,總結瞭Mg(NH2)2-2LiH儲氫材料存在的技術問題併指齣瞭今後的研究方嚮。
Mg(NH2)2-2LiH재료시근년래발전기래적궤충최구응용잠력적고용량저경재료지일。유우구유교합괄적흡방경열역학성능、상대교저적흡방경조작온도、교고적가역저경용량화교우적흡방경순배은정성, Mg(NH2)2-2LiH재료현이성위저경재료연구영역적일개열점。본문종술료Mg(NH2)2-2LiH재료근년래적연구진전,중점관주료재료적조분、정체결구、과(정)립척촌화최화동역학개성등대재료저경성능적영향급저경궤리,총결료Mg(NH2)2-2LiH저경재료존재적기술문제병지출료금후적연구방향。
Mg(NH2)2-2LiH composite is one of the most promising high-capacity hydrogen storage materials developed in recent years. Research on Mg(NH2)2-2LiH material for hydrogen storage is of considerable interest because of its favorable thermodynamic properties, high reversible hydrogen capacity, relatively low operating temperatures, and good cycling stability for dehydrogenation/hydrogenation. In this review, the recent progress in the hydrogen storage properties of Mg(NH2)2-2LiH material was systematical y summarized. The focus is on the effect of material composites, crystal structures, particle (grain) sizes, and catalysts on the hydrogen storage properties of the Mg(NH2)2-2LiH material, and their reaction mechanisms for hydrogen storage. The chal enges in and direction for further improving the hydrogen storage properties of the Mg(NH2)2-2LiH material are also pointed out.