中南民族大学学报(自然科学版)
中南民族大學學報(自然科學版)
중남민족대학학보(자연과학판)
JOURNAL OF SOUTH-CENTRAL UNIVERSITY FOR NATIONALITIES(NATURAL SCIENCE EDITION)
2015年
1期
66-72
,共7页
钟志有%兰椿%龙路%陆轴
鐘誌有%蘭椿%龍路%陸軸
종지유%란춘%룡로%륙축
磁控溅射%氧化锌薄膜%掺杂%结晶质量
磁控濺射%氧化鋅薄膜%摻雜%結晶質量
자공천사%양화자박막%참잡%결정질량
magnetron sputtering%zinc oxide thin films%doping%crystal quality
以氧化锌( ZnO)掺杂氧化镓( Ga2 O3)的陶瓷靶作为溅射靶材,采用射频磁控溅射技术在玻璃衬底上制备了透明导电的掺镓氧化锌( ZnO:Ga)薄膜.通过X射线衍射仪测试研究了衬底温度对薄膜结晶性能及其残余应力的影响.研究结果表明:所有ZnO:Ga薄膜均为六角纤锌矿型的多晶结构并具有(002)方向的择优取向特性,其结晶性能和残余应力与衬底温度密切相关.随着衬底温度的升高,薄膜的(002)择优取向程度和晶粒尺寸呈现出先增大后减小的变化趋势,而薄膜的残余压应力则单调减小.当衬底温度为400℃时,ZnO:Ga薄膜具有最大的晶粒尺寸(75.1 nm)、最大的织构系数TC(002)(2.995)、较小的压应力(-0.185 GPa)和最好的结晶性能.
以氧化鋅( ZnO)摻雜氧化鎵( Ga2 O3)的陶瓷靶作為濺射靶材,採用射頻磁控濺射技術在玻璃襯底上製備瞭透明導電的摻鎵氧化鋅( ZnO:Ga)薄膜.通過X射線衍射儀測試研究瞭襯底溫度對薄膜結晶性能及其殘餘應力的影響.研究結果錶明:所有ZnO:Ga薄膜均為六角纖鋅礦型的多晶結構併具有(002)方嚮的擇優取嚮特性,其結晶性能和殘餘應力與襯底溫度密切相關.隨著襯底溫度的升高,薄膜的(002)擇優取嚮程度和晶粒呎吋呈現齣先增大後減小的變化趨勢,而薄膜的殘餘壓應力則單調減小.噹襯底溫度為400℃時,ZnO:Ga薄膜具有最大的晶粒呎吋(75.1 nm)、最大的織構繫數TC(002)(2.995)、較小的壓應力(-0.185 GPa)和最好的結晶性能.
이양화자( ZnO)참잡양화가( Ga2 O3)적도자파작위천사파재,채용사빈자공천사기술재파리츤저상제비료투명도전적참가양화자( ZnO:Ga)박막.통과X사선연사의측시연구료츤저온도대박막결정성능급기잔여응력적영향.연구결과표명:소유ZnO:Ga박막균위륙각섬자광형적다정결구병구유(002)방향적택우취향특성,기결정성능화잔여응력여츤저온도밀절상관.수착츤저온도적승고,박막적(002)택우취향정도화정립척촌정현출선증대후감소적변화추세,이박막적잔여압응력칙단조감소.당츤저온도위400℃시,ZnO:Ga박막구유최대적정립척촌(75.1 nm)、최대적직구계수TC(002)(2.995)、교소적압응력(-0.185 GPa)화최호적결정성능.
The gallium-doped zinc oxide ( ZnO:Ga) thin films were prepared on glass substrates by magnetron sputtering method using the ceramic target fabricated by sintering the mixture of ZnO and Ga2 O3 nanometer powder.The substrate temperature was varied from 200 ℃ to 500 ℃ during the magnetron sputtering process.The crystal quality and residual stress of the deposited films were investigated by X-ray diffractometer.The results indicated that the crystal quality and residual stress of the samples are closely related to the substrate temperature.As the substrate temperature increasing, the degree of preferred orientation, average grain size and residual stress of the samples change nonmonotonically.The thin film deposited at the substrate temperature of 400 ℃ has the largest grain size (75.1 nm), the maximum texture coefficient TC(002) (2.995), the lower compressive stress (-0.185 GPa) and the best crystal quality.