CAJ | 학술논문

以偶氮苯‐3，5，4′‐三羧酸（H3abt）为配体，在水热条件下合成了一个新颖的配合物[Co（H2abt）2（H2O）4]·H2 O（1），并通过元素分析、红外光谱、热重分析和X射线单晶衍射对其结构进行了表征。结构分析显示，配合物1具有含螺旋孔道的三维超分子网格结构，两种手性的螺旋水链通过配位作用和氢键固定于螺旋孔道中。
이우담분‐3，5，4′‐삼최산（H3abt）위배체，재수열조건하합성료일개신영적배합물[Co（H2abt）2（H2O）4]·H2 O（1），병통과원소분석、홍외광보、열중분석화X사선단정연사대기결구진행료표정。결구분석현시，배합물1구유함라선공도적삼유초분자망격결구，량충수성적라선수련통과배위작용화경건고정우라선공도중。
A novel compound [Co(H2 abt)2 (H2 O)4 ]·H2 O (1) (H3 abt = Azobenzene‐3 ,5 ,4′‐tricarboxylic acid) was synthesized under hydrothermal reaction and characterized by elemental analysis ,infrared spectrum (IR) ,thermogravimetric analysis (TGA) and single‐crystal X‐ray diffraction .Structure analysis shows that complex 1 has the 3D supramolecular network with helical channels ,in which both handedness helical water chains were trapped by the coordina‐tion interactions as well as hydrogen bonds .