哈尔滨商业大学学报(自然科学版)
哈爾濱商業大學學報(自然科學版)
합이빈상업대학학보(자연과학판)
JOURNAL OF HARBIN UNIVERSITY OF COMMERCE(NATURAL SCIENCES EDITION)
2015年
2期
195-200
,共6页
粉末活性碳%表面改性%酸/碱氧化改性%负载单宁酸%六价铬
粉末活性碳%錶麵改性%痠/堿氧化改性%負載單寧痠%六價鉻
분말활성탄%표면개성%산/감양화개성%부재단저산%륙개락
powder activated carbon%surface modification%acid/alkali oxidation modifica-tion%immobilization of food-grade tannic acid%hexavalent chromium
通过HNO3、NaOH氧化和负载食品级单宁酸等改性技术制备改性PAC,考察改性PAC对低温(2℃)水中低质量浓度Cr(VI)及Cr(Ⅲ)离子(0.500 mg/L)的去除性能,选择制备高效吸附低质量浓度Cr( VI)的PAC表面改性技术.试验结果表明,表面负载食品级单宁酸改性( TA-OC)为最佳改性方法,其比表面积、总孔容积和表面极性大小最佳,正交试验确定的TA-OC的最佳制备条件为:单宁酸质量浓度为15 mg/L,pH值为4,温度为40℃,时间为9 h.
通過HNO3、NaOH氧化和負載食品級單寧痠等改性技術製備改性PAC,攷察改性PAC對低溫(2℃)水中低質量濃度Cr(VI)及Cr(Ⅲ)離子(0.500 mg/L)的去除性能,選擇製備高效吸附低質量濃度Cr( VI)的PAC錶麵改性技術.試驗結果錶明,錶麵負載食品級單寧痠改性( TA-OC)為最佳改性方法,其比錶麵積、總孔容積和錶麵極性大小最佳,正交試驗確定的TA-OC的最佳製備條件為:單寧痠質量濃度為15 mg/L,pH值為4,溫度為40℃,時間為9 h.
통과HNO3、NaOH양화화부재식품급단저산등개성기술제비개성PAC,고찰개성PAC대저온(2℃)수중저질량농도Cr(VI)급Cr(Ⅲ)리자(0.500 mg/L)적거제성능,선택제비고효흡부저질량농도Cr( VI)적PAC표면개성기술.시험결과표명,표면부재식품급단저산개성( TA-OC)위최가개성방법,기비표면적、총공용적화표면겁성대소최가,정교시험학정적TA-OC적최가제비조건위:단저산질량농도위15 mg/L,pH치위4,온도위40℃,시간위9 h.
The modification methods used in this work were HNO3/NaOH oxidation modifica-tion and immobilization of food-grade tannic acid.Through the analysis of the adsorption properties of modified carbons for the low concentration Cr( VI)/Cr(Ⅲ) ion(0.500 mg/L) from low temperature water (2℃) , the optimal modification method was confirmed.Test re-sults showed that the carbon immobilized by tannic acid ( TA-OC) has the best adsorption properties and it is chosen as the optimal modified carbon.TA-OC has the best specific surface area, total pore volume and surface polarity.The variance analysis of orthogonal test indicated that the optimal preparation conditions of TA-OC were determined as food-grade tannic concentration of 15 mg/L, pH value of 4.0, temperature of 40 ℃ and the modified time of 9 h.