光谱学与光谱分析
光譜學與光譜分析
광보학여광보분석
SPECTROSCOPY AND SPECTRAL ANALYSIS
2015年
5期
1290-1293
,共4页
刘佳%黄菲%孟林%俞浩然%陈应华
劉佳%黃菲%孟林%俞浩然%陳應華
류가%황비%맹림%유호연%진응화
FeS2-Fe1 - x S%光吸收特征%水热%禁带宽度%光电转换效率
FeS2-Fe1 - x S%光吸收特徵%水熱%禁帶寬度%光電轉換效率
FeS2-Fe1 - x S%광흡수특정%수열%금대관도%광전전환효솔
FeS2-Fe1 - x S%Light absorption characteristics%Hydrothermal%Band gap%Electrical-to-optical conversion efficiency
铁硫系列矿物是重要的金属硫化物,FeS2和Fe1- x S分别是铁硫系列矿物的重要成员。其中黄铁矿(FeS2)具有较大的吸收系数及合适的禁带宽度,适用于做太阳能电池材料,具有较好的应用前景。前人对不同条件下的铁硫系列矿物光伏特性进行了一定的研究,但对于 FeS2和Fe1- x S共存情况下光吸收性能研究较少。FeS2和Fe1- x S分别是铁硫系列矿物的重要成员,由于形成条件较为接近,常共生出现。因此,对FeS2和Fe1- x S光吸收性能的研究具有重要意义。以水热条件下合成微米粒状FeS2-Fe1- x S为样本,分别使用SSX-550扫描电子显微镜、多晶X射线衍射仪(XRD)观测表征粉末晶体的形态、成分和结构。结果表明:所测样品主要为FeS2中立方晶系黄铁矿,含有一定量的斜方晶系磁黄铁矿(Fe1- x S ),样品平均粒度在5~10μm左右。用Cary500型紫外-可见近红外分光光度计在200~2000 nm范围内测出了样品的吸收谱介于1860~1889 nm之间,吸收峰值为1879 nm。根据带隙(eV )公式计算样品的禁带宽度为0.6578 eV ,对应的“极限转换效率”可达到15%左右,利用第一性原理分析样品禁带宽度变化的原因,并与前人研究结果进行对比。分析认为:矿物内部结构是影响光电转化的重要原因,所合成具有FeS2-Fe1- x S异质结构材料的光吸收特性,较天然地质体中含Co和Ni缺陷的黄铁矿光吸收特性好,光电转换效率有所提高,为深入研究Fe-S系列材料的光伏性能提供了科学依据。
鐵硫繫列礦物是重要的金屬硫化物,FeS2和Fe1- x S分彆是鐵硫繫列礦物的重要成員。其中黃鐵礦(FeS2)具有較大的吸收繫數及閤適的禁帶寬度,適用于做太暘能電池材料,具有較好的應用前景。前人對不同條件下的鐵硫繫列礦物光伏特性進行瞭一定的研究,但對于 FeS2和Fe1- x S共存情況下光吸收性能研究較少。FeS2和Fe1- x S分彆是鐵硫繫列礦物的重要成員,由于形成條件較為接近,常共生齣現。因此,對FeS2和Fe1- x S光吸收性能的研究具有重要意義。以水熱條件下閤成微米粒狀FeS2-Fe1- x S為樣本,分彆使用SSX-550掃描電子顯微鏡、多晶X射線衍射儀(XRD)觀測錶徵粉末晶體的形態、成分和結構。結果錶明:所測樣品主要為FeS2中立方晶繫黃鐵礦,含有一定量的斜方晶繫磁黃鐵礦(Fe1- x S ),樣品平均粒度在5~10μm左右。用Cary500型紫外-可見近紅外分光光度計在200~2000 nm範圍內測齣瞭樣品的吸收譜介于1860~1889 nm之間,吸收峰值為1879 nm。根據帶隙(eV )公式計算樣品的禁帶寬度為0.6578 eV ,對應的“極限轉換效率”可達到15%左右,利用第一性原理分析樣品禁帶寬度變化的原因,併與前人研究結果進行對比。分析認為:礦物內部結構是影響光電轉化的重要原因,所閤成具有FeS2-Fe1- x S異質結構材料的光吸收特性,較天然地質體中含Co和Ni缺陷的黃鐵礦光吸收特性好,光電轉換效率有所提高,為深入研究Fe-S繫列材料的光伏性能提供瞭科學依據。
철류계렬광물시중요적금속류화물,FeS2화Fe1- x S분별시철류계렬광물적중요성원。기중황철광(FeS2)구유교대적흡수계수급합괄적금대관도,괄용우주태양능전지재료,구유교호적응용전경。전인대불동조건하적철류계렬광물광복특성진행료일정적연구,단대우 FeS2화Fe1- x S공존정황하광흡수성능연구교소。FeS2화Fe1- x S분별시철류계렬광물적중요성원,유우형성조건교위접근,상공생출현。인차,대FeS2화Fe1- x S광흡수성능적연구구유중요의의。이수열조건하합성미미립상FeS2-Fe1- x S위양본,분별사용SSX-550소묘전자현미경、다정X사선연사의(XRD)관측표정분말정체적형태、성분화결구。결과표명:소측양품주요위FeS2중립방정계황철광,함유일정량적사방정계자황철광(Fe1- x S ),양품평균립도재5~10μm좌우。용Cary500형자외-가견근홍외분광광도계재200~2000 nm범위내측출료양품적흡수보개우1860~1889 nm지간,흡수봉치위1879 nm。근거대극(eV )공식계산양품적금대관도위0.6578 eV ,대응적“겁한전환효솔”가체도15%좌우,이용제일성원리분석양품금대관도변화적원인,병여전인연구결과진행대비。분석인위:광물내부결구시영향광전전화적중요원인,소합성구유FeS2-Fe1- x S이질결구재료적광흡수특성,교천연지질체중함Co화Ni결함적황철광광흡수특성호,광전전환효솔유소제고,위심입연구Fe-S계렬재료적광복성능제공료과학의거。
Fe-S series ,especially FeS2 and Fe1 - x S is the main component of crustal rocks as important metal sulphides .Pyrite (FeS2 ) shows a promising vision in solar cell materials for its high absorption coefficient and suitable band gap .Predecessors have done some researches on the photovoltaic properties of Fe-S series under different conditions .However ,little researches have been done on the coexisted sulphide of FeS2 and Fe1 - xS .FeS2 and Fe1 - xS often appear as symbiotically due to their similar formation conditions .So the study on the optical absorption characteristics of FeS2 and Fe1 - x S are of important significance .In order to study the optical absorption characteristics of FeS2-Fe1 - x S heterostructures ,using the SEM and XRD to characterize the morphology ,composition and structure ,respectively .The results show that the samples were cubic pyrite with a certain amount of pyrhotite (Fe1 - xS) .The crystal partical size was between 5 and 10 nm .Measurement of the absorption spectrum was per-formed using Cary 500 UV-Vis-NIR spectrophotometer ,acquiring the results of 1 860~1 889 nm ,and the absorption peak in 1879nm .According to the band gap (eV) formula ,the band gap value is calculated to be 0.657 8 eV .The extreme electrical-to-optical conversion efficiency achieved was about 15% .By the first principles ,we analysed the reason of the changing of the band gap value ,and then compared the result with previous one .The internal structure of mineral is the important factor affecting the photoelectric conversion .The light absorption characteristics of FeS2-Fe1 - x S heterostructures synthesized under hydrothermal conditions is better than the characteristics from natural pyrite with defects of Co and Ni .The heterostructures can improve the electrical-to-optical conversion efficiency and provide scientific basis for the absorption characteristics research of Fe-S series ma-terials .