勘察科学技术
勘察科學技術
감찰과학기술
SITE INVESTIGATION SCIENCE AND TECHNOLOGY
2015年
2期
14-19
,共6页
黄向青%甘华阳%刘鑫%路剑飞%潘毅
黃嚮青%甘華暘%劉鑫%路劍飛%潘毅
황향청%감화양%류흠%로검비%반의
地下水%钾离子%稀释混合理论%行为
地下水%鉀離子%稀釋混閤理論%行為
지하수%갑리자%희석혼합이론%행위
groundwater%potassium ion%dilution and mixture theory%behavior
依据雷州半岛以东的东海岛滨海地下水测井潮周期取样测试数据,以Cl-为保守离子,应用了物理混合理论方法,探讨了在海水入侵过程中通过孔隙介质时K+的迁移性。结果显示,K+含量呈现波动势态,绝对含量明显低于Cl-、Na+,但相对变化幅度则与两者相近;其保守性低于Na+和Mg2+,实测数据点均位于理论稀释线TDL的下方,通过孔隙介质之后K+具有明显的向固相迁移行为;实测K+以及理论计算的ΔK+与Cl-同样保持线性关系,ΔK+在两个潮周期平均依次为-22.30mg/L和-14.37mg/L,潮周期逐时变化曲线与Ca2+具有反相特征,K+同样参与了阳离子置换,ΔγK+在-1.75~-0.09meq/L之间,其时间变化趋势有线性和对数缓慢单增关系。
依據雷州半島以東的東海島濱海地下水測井潮週期取樣測試數據,以Cl-為保守離子,應用瞭物理混閤理論方法,探討瞭在海水入侵過程中通過孔隙介質時K+的遷移性。結果顯示,K+含量呈現波動勢態,絕對含量明顯低于Cl-、Na+,但相對變化幅度則與兩者相近;其保守性低于Na+和Mg2+,實測數據點均位于理論稀釋線TDL的下方,通過孔隙介質之後K+具有明顯的嚮固相遷移行為;實測K+以及理論計算的ΔK+與Cl-同樣保持線性關繫,ΔK+在兩箇潮週期平均依次為-22.30mg/L和-14.37mg/L,潮週期逐時變化麯線與Ca2+具有反相特徵,K+同樣參與瞭暘離子置換,ΔγK+在-1.75~-0.09meq/L之間,其時間變化趨勢有線性和對數緩慢單增關繫。
의거뇌주반도이동적동해도빈해지하수측정조주기취양측시수거,이Cl-위보수리자,응용료물리혼합이론방법,탐토료재해수입침과정중통과공극개질시K+적천이성。결과현시,K+함량정현파동세태,절대함량명현저우Cl-、Na+,단상대변화폭도칙여량자상근;기보수성저우Na+화Mg2+,실측수거점균위우이론희석선TDL적하방,통과공극개질지후K+구유명현적향고상천이행위;실측K+이급이론계산적ΔK+여Cl-동양보지선성관계,ΔK+재량개조주기평균의차위-22.30mg/L화-14.37mg/L,조주기축시변화곡선여Ca2+구유반상특정,K+동양삼여료양리자치환,ΔγK+재-1.75~-0.09meq/L지간,기시간변화추세유선성화대수완만단증관계。
According to the sampling test data of tidal cycle of groundwater observation-wells in Donghai island coastal area ,east of Leizhou peninsula , taking the Cl -as the conservative ion , using the physical mixture theory method ,the K +′s migratory aptitude is discussed during the seawater intrusion and through the porous media .The results show that the content of K +shows a fluctuant trend .The absolute content of K+is lower than Cl -and Na +obviously , but its relative change range is close with Cl -and Na +.The K+′s conservation is lower than Na +and Mg2+,and the measured data points are all under the TDL . Passing through the porous media ,the K+has the solid migration behavior obviously .The measured K +and the theoretical calculated ΔK+all keep linear relationship with Cl -,and the content of ΔK+is -22. 30mg/L and -14.37mg/L in average in turn in two tidal cycles .The ΔK+′s tidal cycle change curve presents contrary character with Ca 2+.The K+involves in cation exchange too .TheΔγK+is in the range of-1.75~-0.09meq/L,the linear and logarithm present monotone increasing relationship about its change trend with time .