CAJ | 학술논문

采用简单的涂滴法制备出新型的Al、Ta共掺杂的三元铁氧化物(Ta/Al-Fe2O3)可见光响应型光催化薄膜。运用X射线光电子能谱(XPS)和紫外-可见(UV-Vis)光谱等手段对其进行了表征，考察了其光电化学性能，并研究了复合电极光电催化降解亚甲基蓝(MB)废水的反应性能。由表面谱学分析可知， Ta和Al成功掺入Fe2O3中， Ta会改变催化剂表面Al和O的化学环境。在可见光照射下的光电催化(PEC)反应中， Ta/Al-Fe2O3降解MB的反应速率约为Al-Fe2O3的2倍，光电催化共作用的效果优于单纯光催化作用(PC)和电催化(EC)作用的效果。结果表明， Ta掺杂有利于提高Ta/Al-Fe2O3薄膜的光电催化活性。
채용간단적도적법제비출신형적Al、Ta공참잡적삼원철양화물(Ta/Al-Fe2O3)가견광향응형광최화박막。운용X사선광전자능보(XPS)화자외-가견(UV-Vis)광보등수단대기진행료표정，고찰료기광전화학성능，병연구료복합전겁광전최화강해아갑기람(MB)폐수적반응성능。유표면보학분석가지， Ta화Al성공참입Fe2O3중， Ta회개변최화제표면Al화O적화학배경。재가견광조사하적광전최화(PEC)반응중， Ta/Al-Fe2O3강해MB적반응속솔약위Al-Fe2O3적2배，광전최화공작용적효과우우단순광최화작용(PC)화전최화(EC)작용적효과。결과표명， Ta참잡유리우제고Ta/Al-Fe2O3박막적광전최화활성。
A novel visible-light-responsive photoanode (Ta/Al-Fe2O3) was fabricated by co-doping Ta and Al into iron oxide. The properties of the prepared electrodes were examined using X-ray photoelectron spectroscopy (XPS) and ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy. XPS analysis suggested that the surface chemical environments of Al and O were significantly affected by Ta doping. Photoelectrochemical (PEC), electrocatalytic (EC), and photocatalytic (PC) degradations of methylene blue (MB) were performed using Ta/Al-Fe2O3 and Al-Fe2O3 electrodes as the photoanodes. The results indicated that synergetic effects in PEC enhanced the MB degradation efficiency compared with the individual PC or EC processes. The estimated rate constant for MB degradation on Ta/Al-Fe2O3 was about twice that on Al-Fe2O3 under visible-light irradiation in the PEC process. The greatly improved visible-light activity and film stability indicated that Ta doping was an efficient way to improve the PEC activity of Ta/Al-Fe2O3 films.