CAJ | 학술논문

建立凝胶渗透色谱―气相色谱―串联质谱法测定菜籽油中5种高毒农药的检测方法。样品经乙酸乙酯―环己烷（体积比1∶1）溶解，凝胶渗透色谱（GPC）净化，利用GC–MS/MS检测，外标法定量。方法检测限为0.2~1.9μg/kg，在0.05、0.1、0.5 mg/kg三个质量分数水平进行了添加回收实验，样品回收率为75.2%~95.7%，RSD为2.0%~6.1%。该方法具有操作简单，快速，净化效果好，精密度高，重现性好等优点，可应用于菜籽油中的5种高毒农药残留量的检测。
건립응효삼투색보―기상색보―천련질보법측정채자유중5충고독농약적검측방법。양품경을산을지―배기완（체적비1∶1）용해，응효삼투색보（GPC）정화，이용GC–MS/MS검측，외표법정량。방법검측한위0.2~1.9μg/kg，재0.05、0.1、0.5 mg/kg삼개질량분수수평진행료첨가회수실험，양품회수솔위75.2%~95.7%，RSD위2.0%~6.1%。해방법구유조작간단，쾌속，정화효과호，정밀도고，중현성호등우점，가응용우채자유중적5충고독농약잔류량적검측。
The GPC–GC–MS/MS method for the determination of 5 high–toxic pesticide residues in rapeseed oil was established. Sample was dissolved by ethyl acetate–cyclohexane( 1∶1,v/v), purified by GPC and detected by GC–MS/MS,and with external standard method for quantitative. The detection limit was 0.2~1.9 μg/kg. When standard levels were 0.05,0.1,0.5 mg/kg,the average recovery rates were in the range of 75.2%~95.7%,and the relative standard deviations were in the range of 2.0%~6.1%. The method had the advantages of simple operation,rapid,good purifying effect,high precision,good reproducibility,and could be used for the detection of the 5 high–toxic pesticide residues in rapeseed oil.