CAJ | 학술논문

在普通杯芳烃骨架中引入硫原子可以改善普通杯芳烃的配合性能。文中首先合成了硫杂杯[4]芳烃四酰肼衍生物3,在弱酸的催化下继续与化合物4反应,高产率地合成了同时含酰胺和席夫碱单元的硫杂杯[4]芳烃冠醚衍生物5,新化合物的结构经1H NMR、元素分析、ESI-MS等表征证实。同时探讨了新型硫杂杯[4]芳烃衍生物5与系列-α氨基酸的配合性能。
재보통배방경골가중인입류원자가이개선보통배방경적배합성능。문중수선합성료류잡배[4]방경사선정연생물3,재약산적최화하계속여화합물4반응,고산솔지합성료동시함선알화석부감단원적류잡배[4]방경관미연생물5,신화합물적결구경1H NMR、원소분석、ESI-MS등표정증실。동시탐토료신형류잡배[4]방경연생물5여계렬-α안기산적배합성능。
Introduction of sulfur atom could improve the matching performance of calixarenes. Firsthy,the hiacalix[4] arene hydra-zides derivative 3 was synthesized. By treating thiacalix[4] arene hydrazides derivative 3 with aryl aldehyde derivatives 4 in weak acid catalyst,the novel thiacalix[4] crowns derivatives 5 containing amides and schiff-base units were synthesized in high yields. The structure of the new compounds were confirmed by elemental analyses,ESI-MS,1 H NMR spectra. At the same time the compl-exation properties of novel thiacalix[4]arene derivatives 5 and series of alpha amino acids were explored.