无机化学学报
無機化學學報
무궤화학학보
JOURNAL OF INORGANIC CHEMISTRY
2015年
5期
1049-1054
,共6页
马志宏%刘英春%李素贞%韩占刚%郑学忠%林进
馬誌宏%劉英春%李素貞%韓佔剛%鄭學忠%林進
마지굉%류영춘%리소정%한점강%정학충%림진
茚基%羰基钌%X-射线衍射%结构
茚基%羰基釕%X-射線衍射%結構
인기%탄기조%X-사선연사%결구
indenyl%ruthenium carbonyl%X-ray diffraction%structure
配体C9H7R(R=Ph (1),4-tolyl (2),4-chlorophenyl (3),4-methoxyphenyl (4),2-thienyl (5))分别与Ru3(CO)12在甲苯或二甲苯中加热回流,得到了5个双核配合物[(η5-C9H6R)Ru(CO)]2(μ-CO)2(R=Ph(6),4-tolyl (7),4-chlorophenyl (8),4-methoxyphenyl (9),2-thienyl (10)).通过元素分析、红外光谱、核磁共振氢谱对配合物的结构进行了表征,并用X-射线单晶衍射法测定了配合物6,7和10的结构.
配體C9H7R(R=Ph (1),4-tolyl (2),4-chlorophenyl (3),4-methoxyphenyl (4),2-thienyl (5))分彆與Ru3(CO)12在甲苯或二甲苯中加熱迴流,得到瞭5箇雙覈配閤物[(η5-C9H6R)Ru(CO)]2(μ-CO)2(R=Ph(6),4-tolyl (7),4-chlorophenyl (8),4-methoxyphenyl (9),2-thienyl (10)).通過元素分析、紅外光譜、覈磁共振氫譜對配閤物的結構進行瞭錶徵,併用X-射線單晶衍射法測定瞭配閤物6,7和10的結構.
배체C9H7R(R=Ph (1),4-tolyl (2),4-chlorophenyl (3),4-methoxyphenyl (4),2-thienyl (5))분별여Ru3(CO)12재갑분혹이갑분중가열회류,득도료5개쌍핵배합물[(η5-C9H6R)Ru(CO)]2(μ-CO)2(R=Ph(6),4-tolyl (7),4-chlorophenyl (8),4-methoxyphenyl (9),2-thienyl (10)).통과원소분석、홍외광보、핵자공진경보대배합물적결구진행료표정,병용X-사선단정연사법측정료배합물6,7화10적결구.
