粉末冶金材料科学与工程
粉末冶金材料科學與工程
분말야금재료과학여공정
POWDER METALLURGY MATERIALS SCIENCE AND ENGINEERING
2015年
2期
258-265
,共8页
潘修河%涂浩%苏旭平%彭浩平%吴长军%王建华
潘脩河%塗浩%囌旭平%彭浩平%吳長軍%王建華
반수하%도호%소욱평%팽호평%오장군%왕건화
热浸镀锌%锌铝池%面渣%底渣%相组成
熱浸鍍鋅%鋅鋁池%麵渣%底渣%相組成
열침도자%자려지%면사%저사%상조성
hot dip galvanizing%zinc-aluminium bath%surface dross%bottom dross%phase constituent
采用扫描电镜(SEM)和X射线能谱仪(EDS)分别对480~620℃范围内的Zn-22.3%Al、530~620℃范围内的Zn-30%Al和620℃下的Zn-55%Al(Al含量均为质量分数)镀锌铝池中锌渣的组成相及其形成规律进行系统分析与研究。结果表明,Zn-22.3%Al锌铝池在480℃和500℃下形成与由τ5和τ6相组成的面渣,在520℃形成的面渣为τ5相;Zn-30%Al锌铝池在530℃和550℃下也生成由τ5和τ6相组成的面渣,但570℃下面渣仅为τ5相。Zn-22.3%Al锌铝池由于密度低,在620℃时仅生成面渣(τ2+FeAl3);Zn-30%Al锌铝池在620℃时除了生成面渣(τ5+FeAl3)外,中间层还生成τ5和τ6相锌渣;Zn-55%Al锌铝池在620℃下除了形成底渣τ5相以外,中间层还生成τ6相锌渣。
採用掃描電鏡(SEM)和X射線能譜儀(EDS)分彆對480~620℃範圍內的Zn-22.3%Al、530~620℃範圍內的Zn-30%Al和620℃下的Zn-55%Al(Al含量均為質量分數)鍍鋅鋁池中鋅渣的組成相及其形成規律進行繫統分析與研究。結果錶明,Zn-22.3%Al鋅鋁池在480℃和500℃下形成與由τ5和τ6相組成的麵渣,在520℃形成的麵渣為τ5相;Zn-30%Al鋅鋁池在530℃和550℃下也生成由τ5和τ6相組成的麵渣,但570℃下麵渣僅為τ5相。Zn-22.3%Al鋅鋁池由于密度低,在620℃時僅生成麵渣(τ2+FeAl3);Zn-30%Al鋅鋁池在620℃時除瞭生成麵渣(τ5+FeAl3)外,中間層還生成τ5和τ6相鋅渣;Zn-55%Al鋅鋁池在620℃下除瞭形成底渣τ5相以外,中間層還生成τ6相鋅渣。
채용소묘전경(SEM)화X사선능보의(EDS)분별대480~620℃범위내적Zn-22.3%Al、530~620℃범위내적Zn-30%Al화620℃하적Zn-55%Al(Al함량균위질량분수)도자려지중자사적조성상급기형성규률진행계통분석여연구。결과표명,Zn-22.3%Al자려지재480℃화500℃하형성여유τ5화τ6상조성적면사,재520℃형성적면사위τ5상;Zn-30%Al자려지재530℃화550℃하야생성유τ5화τ6상조성적면사,단570℃하면사부위τ5상。Zn-22.3%Al자려지유우밀도저,재620℃시부생성면사(τ2+FeAl3);Zn-30%Al자려지재620℃시제료생성면사(τ5+FeAl3)외,중간층환생성τ5화τ6상자사;Zn-55%Al자려지재620℃하제료형성저사τ5상이외,중간층환생성τ6상자사。
The phase constituents and formation of zinc dross in Zn-22.3% Al bath at temperature range of 480~620℃, Zn-30% Al bath at the range of 570~620℃ and Zn-55% Al bath at 620℃ have been analyzed systemically with scanning electron microscope (SEM) and energy dispersive spectrometer (EDS). The results show that the zinc dross formed on the surface of Zn-22.3% Al bath at 480℃ and 500℃ are mainly composed ofτ5 andτ6 phase, and onlyτ5 phase at 520℃. Similarly, the zinc dross formed on the surface of Zn-30% Al bath at 530℃ and 550℃ are mainly composed ofτ5 andτ6 phase, and onlyτ5 phase at 570℃. The zinc dross formed on the surface of Zn-22.3% Al at 620℃ are mainly composed ofτ2 and FeAl3 phase. The zinc dross formed on the surface of Zn-30% Al at 620℃ are mainly composed ofτ5 and FeAl3 phase. However,τ5 andτ6phases exist in the middle layer of Zn-30% Al bath at 620℃. The zinc dross formed at the bottom of Zn-55% Al bath is composed ofτ5 phase at 620℃. Besides,τ6phase exists in the middle of the bath.