中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2015年
5期
1345-1354
,共10页
艾纯明%吴爱祥%王贻明%王少勇
艾純明%吳愛祥%王貽明%王少勇
애순명%오애상%왕이명%왕소용
细菌脱硫%硫化矿%表面脱硫率%动力学
細菌脫硫%硫化礦%錶麵脫硫率%動力學
세균탈류%류화광%표면탈류솔%동역학
bacterial desulfurization%sulfide ore%surface desulfurization rate%reaction kinetics
为解决硫化矿井下堆存易发生自燃这一问题,进行了高含硫矿石的细菌脱硫试验,对比了不同矿石粒径条件下的脱硫效果,对脱硫反应表面进行了扫描电镜观察,并对细菌脱硫反应进行动力学分析。结果表明:细菌液计脱硫率与矿石粒径呈反比,当矿石粒径为3 mm时,取得了最大脱硫率为22.56%;脱硫反应对矿石表面侵蚀严重,矿石表面的硫含量由43%左右降低至15%以下;6组试验矿石的表面脱硫率均为65%左右,矿石的可燃性降低;反应受内扩散和化学反应共同控制,其中内扩散为主要因素。
為解決硫化礦井下堆存易髮生自燃這一問題,進行瞭高含硫礦石的細菌脫硫試驗,對比瞭不同礦石粒徑條件下的脫硫效果,對脫硫反應錶麵進行瞭掃描電鏡觀察,併對細菌脫硫反應進行動力學分析。結果錶明:細菌液計脫硫率與礦石粒徑呈反比,噹礦石粒徑為3 mm時,取得瞭最大脫硫率為22.56%;脫硫反應對礦石錶麵侵蝕嚴重,礦石錶麵的硫含量由43%左右降低至15%以下;6組試驗礦石的錶麵脫硫率均為65%左右,礦石的可燃性降低;反應受內擴散和化學反應共同控製,其中內擴散為主要因素。
위해결류화광정하퇴존역발생자연저일문제,진행료고함류광석적세균탈류시험,대비료불동광석립경조건하적탈류효과,대탈류반응표면진행료소묘전경관찰,병대세균탈류반응진행동역학분석。결과표명:세균액계탈류솔여광석립경정반비,당광석립경위3 mm시,취득료최대탈류솔위22.56%;탈류반응대광석표면침식엄중,광석표면적류함량유43%좌우강저지15%이하;6조시험광석적표면탈류솔균위65%좌우,광석적가연성강저;반응수내확산화화학반응공동공제,기중내확산위주요인소。
Acidophilus bacteria desulfurization column leaching was used to explore the effect of the desulfurization of metal sulfide ore and the feasibility of inhibiting the spontaneous combustion. The ore surface of the desulfurization of ore with different particles sizes and the kinetics of desulfurization were analyzed. The results show that the bacterial desulfurization rate is inversely proportional to the ore particle size. The desulfurization rate achieves the maximum of 22.56% when the ore particle size is 3mm. The sulfur content of the ore surface reduces from about 43% to 15% or less. The surface desulfurization rate of 6 groups is 65%. The ore surface is eroded severely after the desulfurization reaction. The internal diffusion influences the desulfurization reaction most, followed by the chemical reaction.