中国有色金属学报
中國有色金屬學報
중국유색금속학보
THE CHINESE JOURNAL OF NONFERROUS METALS
2015年
5期
1308-1313
,共6页
张春华%单丽娜%吴臣亮%张松%关锰%谭俊哲
張春華%單麗娜%吳臣亮%張鬆%關錳%譚俊哲
장춘화%단려나%오신량%장송%관맹%담준철
FeCoCrAlCu%Cu单元素基合金%激光高熵合金化%固溶体%纳米硬度
FeCoCrAlCu%Cu單元素基閤金%激光高熵閤金化%固溶體%納米硬度
FeCoCrAlCu%Cu단원소기합금%격광고적합금화%고용체%납미경도
FeCoCrAlCu%Cu single-element base alloy%laser high entropy alloying%solid solution%nanoindentation
采用Nd:YAG激光辐照法在Cu单元素基合金表面制备FeCoCrAlCu高熵合金化涂层。利用扫描电镜、能谱仪、X射线衍射仪、显微硬度计及纳米压痕仪等研究FeCoCrAlCu激光高熵合金化层形成机制及性能。结果表明:采用优化的激光辐照工艺参数对等摩尔比的 Fe、Co、Cr、Al 四元合金粉末进行激光辐照合金化,可制备出含有基体主元Cu的FeCoCrAlCu高熵合金化涂层。合金化涂层由FCC+BCC简单结构固溶体组成,其显微组织主要以颗粒状组织为主,且与基体呈良好的冶金结合。FeCoCrAlCu 激光高熵合金化层的硬度是基体材料的7倍以上,其弹性模量、弹性比和同样深度承受的最大载荷远高于基体材料的,具有良好的强度和韧性。
採用Nd:YAG激光輻照法在Cu單元素基閤金錶麵製備FeCoCrAlCu高熵閤金化塗層。利用掃描電鏡、能譜儀、X射線衍射儀、顯微硬度計及納米壓痕儀等研究FeCoCrAlCu激光高熵閤金化層形成機製及性能。結果錶明:採用優化的激光輻照工藝參數對等摩爾比的 Fe、Co、Cr、Al 四元閤金粉末進行激光輻照閤金化,可製備齣含有基體主元Cu的FeCoCrAlCu高熵閤金化塗層。閤金化塗層由FCC+BCC簡單結構固溶體組成,其顯微組織主要以顆粒狀組織為主,且與基體呈良好的冶金結閤。FeCoCrAlCu 激光高熵閤金化層的硬度是基體材料的7倍以上,其彈性模量、彈性比和同樣深度承受的最大載荷遠高于基體材料的,具有良好的彊度和韌性。
채용Nd:YAG격광복조법재Cu단원소기합금표면제비FeCoCrAlCu고적합금화도층。이용소묘전경、능보의、X사선연사의、현미경도계급납미압흔의등연구FeCoCrAlCu격광고적합금화층형성궤제급성능。결과표명:채용우화적격광복조공예삼수대등마이비적 Fe、Co、Cr、Al 사원합금분말진행격광복조합금화,가제비출함유기체주원Cu적FeCoCrAlCu고적합금화도층。합금화도층유FCC+BCC간단결구고용체조성,기현미조직주요이과립상조직위주,차여기체정량호적야금결합。FeCoCrAlCu 격광고적합금화층적경도시기체재료적7배이상,기탄성모량、탄성비화동양심도승수적최대재하원고우기체재료적,구유량호적강도화인성。
FeCoCrAlCu high entropy alloying coating was synthesized by Nd:YAG laser irradiation method on Cu single-element base alloy. Formation mechanism and properties of FeCoCrAlCu laser high entropy alloying layer were investigated using SEM, EDS, XRD, microhardness tester and nanoindentation tester. The results show that FeCoCrAlCu high entropy alloying coating can be synthesized on the surface of Cu single-element base alloy using equal molar ratio of Fe, Co, Cr, Al quaternary alloy powders by laser irradiation alloying with optimized processing parameters. The alloying coating is composed of FCC+BCC simple structural solid solutions, and the microstructure is mainly granuliform. A good metallurgical bonding between the layer and the substrate can be achieved. The microhardness of FeCoCrAlCu layer is 7 times higher than that of the substrate, and the elastic modulus, elasticity ratio and the maximum load subjected at the same depth of the layer are higher than those of Cu substrate, indicating that the alloying coating has good strength and toughness.