CAJ | 학술논문

以惰性金属、氧化-还原体系和多孔碳材料作为准参比电极，以二茂铁的氧化-还原半峰电位值为内标，对准参比电极在季铵盐有机电解液中的稳定性进行研究。结果显示，金属准参比电极无法建立稳定的电荷平衡体系，其参比电位稳定性较差；氧化-还原体系可以在一定时间和范围内具有稳定的电荷平衡体系，但长时间工作电荷平衡体系会被破坏，导致参比电位稳定性变差；高比表面积多孔碳材料准参比电极具有大量的双电层电容，因而可以建立稳定的电荷平衡体系，具有良好的参比电位稳定性。
이타성금속、양화-환원체계화다공탄재료작위준삼비전겁，이이무철적양화-환원반봉전위치위내표，대준삼비전겁재계안염유궤전해액중적은정성진행연구。결과현시，금속준삼비전겁무법건립은정적전하평형체계，기삼비전위은정성교차；양화-환원체계가이재일정시간화범위내구유은정적전하평형체계，단장시간공작전하평형체계회피파배，도치삼비전위은정성변차；고비표면적다공탄재료준삼비전겁구유대량적쌍전층전용，인이가이건립은정적전하평형체계，구유량호적삼비전위은정성。
The stability of quasi-reference electrode based on inert metal, oxidation-reduction system, and porous carbon materials was investigated by using Fc/Fc+ as an internal standard in organic electrolyte. The results show the reference electrode of inert metal is not able to establish a stable charge-balancing process, so its stability of reference potential is poor; the charge-balance of oxidation-reduction system is able to maintain within a short time, however the charge-balance is destroyed for long testing time, which leads to the deterioration of stability of reference potential; activated carbon has a good stability of the reference potential due to its large number of electric double layer which is able to establish an a stable charge balance system.