真空
真空
진공
VACUUM
2015年
3期
63-66
,共4页
氧化石墨烯%等离子体%还原
氧化石墨烯%等離子體%還原
양화석묵희%등리자체%환원
graphene oxide%hydrogen plasma%reduction
还原氧化石墨烯是一种宏量制备石墨烯的有效方法,目前报道的还原方法包括物理和化学的方法,都存在各种各样的问题,比如危害环境,不兼容低温工艺等。本文提出了一种低温氧化石墨烯还原的方法。利用氢等离子体和氧化石墨烯反应,去除含氧官能团,实现还原氧化石墨烯。经过氢等离子体还原后,表征各个含氧官能团的吸收峰强度下降或者消失, Raman光谱上D峰强度的增加,都证实氧化石墨烯被还原。还原后薄膜电阻降低,确认了该方法的可行性。
還原氧化石墨烯是一種宏量製備石墨烯的有效方法,目前報道的還原方法包括物理和化學的方法,都存在各種各樣的問題,比如危害環境,不兼容低溫工藝等。本文提齣瞭一種低溫氧化石墨烯還原的方法。利用氫等離子體和氧化石墨烯反應,去除含氧官能糰,實現還原氧化石墨烯。經過氫等離子體還原後,錶徵各箇含氧官能糰的吸收峰彊度下降或者消失, Raman光譜上D峰彊度的增加,都證實氧化石墨烯被還原。還原後薄膜電阻降低,確認瞭該方法的可行性。
환원양화석묵희시일충굉량제비석묵희적유효방법,목전보도적환원방법포괄물리화화학적방법,도존재각충각양적문제,비여위해배경,불겸용저온공예등。본문제출료일충저온양화석묵희환원적방법。이용경등리자체화양화석묵희반응,거제함양관능단,실현환원양화석묵희。경과경등리자체환원후,표정각개함양관능단적흡수봉강도하강혹자소실, Raman광보상D봉강도적증가,도증실양화석묵희피환원。환원후박막전조강저,학인료해방법적가행성。
The reduction of graphene is an efficient method for macro graphene preparation. There are some problems,in the re-duction routes at present, including physical and chemical reduction , such as non-friendly environment and non-adaption to low temperature processes. Herein, we reduce the graphene oxide by hydrogen ions reacting with the oxygen group in graphene oxide. The results show that the absorption peak, indicating different oxygen group, and the resistance which proved that the graphene oxide was reduced during hydrogen plasma processing,are all decreased, and the G peak in Raman spectra is increased, So low temperature hydrogen plasma is determined to be a feasible method to reduce graphene oxide.