CAJ | 학술논문

制备了一系列烷氧基轴向取代硅酞菁，改善了硅酞菁在有机溶剂中的溶解性；轴向取代的金属酞菁配合物相对于周边取代的金属酞菁配合物更易于制备。对这3个化合物进行了系统的结构表征（核磁氢谱、红外光谱、液相色谱－质谱联用），证实了这3个化合物是目标产物，并在不同溶剂中对它们进行紫外光谱、荧光光谱测试。
제비료일계렬완양기축향취대규태정，개선료규태정재유궤용제중적용해성；축향취대적금속태정배합물상대우주변취대적금속태정배합물경역우제비。대저3개화합물진행료계통적결구표정（핵자경보、홍외광보、액상색보－질보련용），증실료저3개화합물시목표산물，병재불동용제중대타문진행자외광보、형광광보측시。
In this paper, a series of alkoxy phthalocyanine with axially substituted silicon were prepared and synthesized,and their solubility in common organic solvent was improved. Compared with the preparation of pe-ripherally substituted metal phthalocyanine complexes ,that of these axially substituted metal phthalocyanine complexes was easier. Their chemical structures were characterized by 1H NMR,IR,LC mass. Furthermore, their UV spectra and fluorescence spectra in different solvents were investigated.