CAJ | 학술논문

为了解黄花三宝木(Trigonostemon lutescensY. T. Chang et J. Y. Liang)的化学成分，采用硅胶柱色谱与Sephadex LH-20凝胶柱色谱从黄花三宝木乙醇提取物的石油醚与正丁醇萃取部分共分离11个化合物，其结构分别鉴定为：ent-kaurane-3β,16β-diol (1)、(3R,6R,7E)-3-hydroxy-4,7-megastigmadien-9-one (2)、palmarumycin JC2(3)、(±)-3-(3,4,5-trimethoxyphenyl)-1,2-propanediol (4)、赤式-愈创木基甘油-β-O-4′-松柏基醚(5)、苏式-愈创木基甘油-β-O-4′-松柏基醚(6)、3-hydroxymethyl-5-(3-hydroxypropyl)-7-methoxy-2-{3-methoxy-4-[1-(3,4-dimethoxybenzyl)-2-hydroxyethyl]phenyl}-2,3-dihydrobenzofuran (7)、ancistrocline (8)、hamatine (9)、东莨菪苷(10)和紫丁香苷(11)。上述化合物均为首次从该种植物中分离得到，其中化合物1、3~11为首次从该属植物中分离得到。
위료해황화삼보목(Trigonostemon lutescensY. T. Chang et J. Y. Liang)적화학성분，채용규효주색보여Sephadex LH-20응효주색보종황화삼보목을순제취물적석유미여정정순췌취부분공분리11개화합물，기결구분별감정위：ent-kaurane-3β,16β-diol (1)、(3R,6R,7E)-3-hydroxy-4,7-megastigmadien-9-one (2)、palmarumycin JC2(3)、(±)-3-(3,4,5-trimethoxyphenyl)-1,2-propanediol (4)、적식-유창목기감유-β-O-4′-송백기미(5)、소식-유창목기감유-β-O-4′-송백기미(6)、3-hydroxymethyl-5-(3-hydroxypropyl)-7-methoxy-2-{3-methoxy-4-[1-(3,4-dimethoxybenzyl)-2-hydroxyethyl]phenyl}-2,3-dihydrobenzofuran (7)、ancistrocline (8)、hamatine (9)、동랑탕감(10)화자정향감(11)。상술화합물균위수차종해충식물중분리득도，기중화합물1、3~11위수차종해속식물중분리득도。
In order to understand the chemical constituents ofTrigonostemon lutescens, eleven compounds were isolated from its 95% EtOH extract by silica gel and sephadex LH-20 column chromatography. On the basis of spectral data, they were identiifed asent-kaurane-3β,16β-diol (1), (3R,6R,7E)-3-hydroxy-4,7-megastigmadien-9-one (2), palmarumycin JC2 (3), (±)-3-(3,4,5-trimethoxyphenyl)-1,2-propanediol (4), erythro-guaiacylglycerol-β-O-4′-coniferyl ether (5), threo-guaiacylglycerol-β-O-4′-coniferyl ether (6), 3-hydroxymethyl-5-(3-hydroxypropyl)-7-methoxy-2-{3-methoxy-4-[1-(3,4-dimethoxybenzyl)-2-hydroxyethyl]phenyl}-2,3-dihydrobenzofuran (7), ancistrocline (8), hamatine (9), scopolin (10), syringin (11). All the compounds were isolated from this plant for the ifrst time, and they were isolated from the genusTrigonostemonfor the ifrst time except of compound12.