洁净煤技术
潔淨煤技術
길정매기술
CLEAN COAL TECHNOLOGY
2015年
3期
79-82
,共4页
赵博%杨永忠%刘丽婷%白斌%张小庆%王崇侠
趙博%楊永忠%劉麗婷%白斌%張小慶%王崇俠
조박%양영충%류려정%백빈%장소경%왕숭협
拉曼光谱%煤结构%高碳物料%煤化工
拉曼光譜%煤結構%高碳物料%煤化工
랍만광보%매결구%고탄물료%매화공
Raman spectroscopy%coal structure%high-carbon material%coal chemical industry
拉曼光谱对碳材料的结构有序状态非常敏感,是表征碳材料常用的技术之一。煤是一种由多种官能团和化学键组成的复杂的有机大分子,具有高碳物质的特征,因此,拉曼光谱在煤的结构分析中有广泛应用,同时煤结构的分析对煤炭的高效清洁利用具有重要意义。介绍了煤的组成和结构,综述了拉曼光谱在煤的结构分析、煤的热解和气化等研究中的应用,并对原位拉曼光谱和联用技术等在煤化工领域的应用前景进行了展望。
拉曼光譜對碳材料的結構有序狀態非常敏感,是錶徵碳材料常用的技術之一。煤是一種由多種官能糰和化學鍵組成的複雜的有機大分子,具有高碳物質的特徵,因此,拉曼光譜在煤的結構分析中有廣汎應用,同時煤結構的分析對煤炭的高效清潔利用具有重要意義。介紹瞭煤的組成和結構,綜述瞭拉曼光譜在煤的結構分析、煤的熱解和氣化等研究中的應用,併對原位拉曼光譜和聯用技術等在煤化工領域的應用前景進行瞭展望。
랍만광보대탄재료적결구유서상태비상민감,시표정탄재료상용적기술지일。매시일충유다충관능단화화학건조성적복잡적유궤대분자,구유고탄물질적특정,인차,랍만광보재매적결구분석중유엄범응용,동시매결구적분석대매탄적고효청길이용구유중요의의。개소료매적조성화결구,종술료랍만광보재매적결구분석、매적열해화기화등연구중적응용,병대원위랍만광보화련용기술등재매화공영역적응용전경진행료전망。
Raman spectroscopy,which is sensitive to the carbon material structure order,is one of the technologies commonly used in the characterization of carbon materials. Coal is a complex organic macromolecular composed of a variety of functional groups and chemical bonds and it has the characteristics of high carbon materials. Therefore,Raman spectroscopy is generally used in the analysis of coal struc-ture. Meanwhile,the analysis of coal structure is significant for efficient and clean utilization of coal. This paper introduced the composition and structure of coal first,then summarized the applications of Raman spectroscopy in the research of coal structure pyrolysis and gasifica-tion. The application of in situ Raman spectroscopy and coupling technique in coal chemical industry was prospected.