东南大学学报(自然科学版)
東南大學學報(自然科學版)
동남대학학보(자연과학판)
JOURNAL OF SOUTHEAST UNIVERSITY
2015年
3期
569-574
,共6页
水泥基材料%界面过渡区%碳化%背散射图像
水泥基材料%界麵過渡區%碳化%揹散射圖像
수니기재료%계면과도구%탄화%배산사도상
cement-based material%interfacial transition zone%carbonization%backscattered electron image
为研究界面过渡区微结构在碳化过程中的演变规律,运用背散射( BSE )图像分析技术,使用灰度值统计方法,对比分析了水胶比ρ=0.53,0.35,0.23时混凝土试件中界面过渡区和基体在碳化前后的微结构特征.结果表明,当ρ=0.53,0.35时,试件界面过渡区的孔隙率分别从碳化前的24.97%和16.07%减小到碳化后的20.29%和12.27%,而当ρ=0.23时试件碳化后孔隙率则有所提高.同时,各试件界面过渡区和基体的未水化水泥含量在碳化后均有所下降.因此,在加速碳化条件下,不同水胶比试件的微结构演变规律存在较大差异,界面过渡区和基体的碳化现象也有所差别,且当ρ=0.53时两者的碳化现象最明显,ρ=0.23时碳化现象最不明显.
為研究界麵過渡區微結構在碳化過程中的縯變規律,運用揹散射( BSE )圖像分析技術,使用灰度值統計方法,對比分析瞭水膠比ρ=0.53,0.35,0.23時混凝土試件中界麵過渡區和基體在碳化前後的微結構特徵.結果錶明,噹ρ=0.53,0.35時,試件界麵過渡區的孔隙率分彆從碳化前的24.97%和16.07%減小到碳化後的20.29%和12.27%,而噹ρ=0.23時試件碳化後孔隙率則有所提高.同時,各試件界麵過渡區和基體的未水化水泥含量在碳化後均有所下降.因此,在加速碳化條件下,不同水膠比試件的微結構縯變規律存在較大差異,界麵過渡區和基體的碳化現象也有所差彆,且噹ρ=0.53時兩者的碳化現象最明顯,ρ=0.23時碳化現象最不明顯.
위연구계면과도구미결구재탄화과정중적연변규률,운용배산사( BSE )도상분석기술,사용회도치통계방법,대비분석료수효비ρ=0.53,0.35,0.23시혼응토시건중계면과도구화기체재탄화전후적미결구특정.결과표명,당ρ=0.53,0.35시,시건계면과도구적공극솔분별종탄화전적24.97%화16.07%감소도탄화후적20.29%화12.27%,이당ρ=0.23시시건탄화후공극솔칙유소제고.동시,각시건계면과도구화기체적미수화수니함량재탄화후균유소하강.인차,재가속탄화조건하,불동수효비시건적미결구연변규률존재교대차이,계면과도구화기체적탄화현상야유소차별,차당ρ=0.53시량자적탄화현상최명현,ρ=0.23시탄화현상최불명현.
To study the microstructure evolution of the interfacial transition zone ( ITZ) in the car-bonization process, the microstructural features of the ITZs and the matrixes in the concrete samples before and after carbonization with the water-binder ratio ρ of 0.53, 0.35 and 0.23 are analyzed comparatively by using the gray value statistics method and the backscattered electron ( BSE) image analysis technique.The results show that the porosities of the ITZs in the concrete samples reduce from 24.97%and 16.07%to 20.29% and 12.27% after carbonization when ρ=0.53 and 0.35, respectively, while it increases whenρ=0.23.Meanwhile, all of the unhydrated cement contents of the ITZs and the matrixes in the concrete samples with three kinds of water-binder ratios decrease af-ter carbonization.Therefore, under the accelerated carbonization condition, the microstructure evo-lutions of the samples with different water-binder ratios are different.The carbonization appearance of the ITZs and the matrixes are also different.The carbonization appearance of the ITZ and that of the matrix are the most obvious when ρ=0.53, while they are the least obvious for when=0.23.