CAJ | 학술논문

选用生物质废弃物椰壳制备活性炭脱汞吸附剂，并在不同温度下进行载硫改性。采用N2吸附／脱附、热重质谱联用（ TG-MS）、X射线近边吸收结构（ XANES）等方法对吸附剂进行孔隙结构和硫存在形态表征。在模拟烟气管道喷射实验装置上进行汞吸附脱除实验研究。结果表明，载硫温度500℃时椰壳活性炭汞吸附效率优于商用富硫活性炭。活性炭汞吸附脱除能力由孔隙结构、硫含量与硫存在形态共同决定。硫含量随着载硫温度的提高而降低，孔隙结构参数得到优化。元素硫、噻吩与硫酸盐为活性炭硫的主要存在形态，噻吩为有机硫的主要形态。元素硫与噻吩均有利于汞吸附脱除，其中元素硫效果最优。模拟烟气组分的加入促进了活性炭脱汞效率的提高。
선용생물질폐기물야각제비활성탄탈홍흡부제，병재불동온도하진행재류개성。채용N2흡부／탈부、열중질보련용（ TG-MS）、X사선근변흡수결구（ XANES）등방법대흡부제진행공극결구화류존재형태표정。재모의연기관도분사실험장치상진행홍흡부탈제실험연구。결과표명，재류온도500℃시야각활성탄홍흡부효솔우우상용부류활성탄。활성탄홍흡부탈제능력유공극결구、류함량여류존재형태공동결정。류함량수착재류온도적제고이강저，공극결구삼수득도우화。원소류、새분여류산염위활성탄류적주요존재형태，새분위유궤류적주요형태。원소류여새분균유리우홍흡부탈제，기중원소류효과최우。모의연기조분적가입촉진료활성탄탈홍효솔적제고。
Coconut shell as a kind of biomass wastes was chosen to prepare the mercury removal ac-tivated carbon, which was then modified with elemental sulfur at different temperatures.The pore structure and sulfur forms of adsorbents were characterized by nitrogen ( N2 ) adsorption/desorption, thermogravimetry-mass spectrometry ( TG-MS ) , and X-ray absorption near-edge structure ( XANES) .Experimental studies on Hg removal were conducted in a duct injection system flowed with simulated fuel gas.The results show that coconut shell activated carbon modified with elemental sulfur at 500 ℃ performs a higher mercury adsorption efficiency than commercial activated carbon with high sulfur content.The mercury removal capacity of activated carbon is controlled by its pore structure, sulfur content, and sulfur forms.With the increase of the impregnation temperature, the total sulfur content decreases while the pore structure parameters are optimized.Elemental sulfur, thiophene, and sulfate are the main forms of sulfur deposited on the carbon surface, and thiophene is the main form of organic sulfur.Elemental sulfur and thiophene benefit the Hg adsorption capacity, and elemental sulfur is more effective.The addition of simulated flue gas components can promote mercury adsorption efficiency of activated carbon.