岩矿测试
巖礦測試
암광측시
ROCK AND MINERAL ANALYSIS
2015年
3期
302-307
,共6页
王祝%李明礼%邵蓓%卓玛曲西%姜贞贞%刘高令%多吉
王祝%李明禮%邵蓓%卓瑪麯西%薑貞貞%劉高令%多吉
왕축%리명례%소배%탁마곡서%강정정%류고령%다길
地热水%主次量元素%电感耦合等离子体发射光谱法%保存介质%保存时间%硝酸
地熱水%主次量元素%電感耦閤等離子體髮射光譜法%保存介質%保存時間%硝痠
지열수%주차량원소%전감우합등리자체발사광보법%보존개질%보존시간%초산
geothermal water%major and minor elements%Inductively Coupled Plasma-Optical Emission Spectrometry%preservation medium%preservation time%nitrate
西藏地热水的矿化度普遍较高,矿物质种类丰富,本文建立了采用电感耦合等离子体发射光谱(ICP -OES)同时测定西藏日多温泉地热水中11种主次量元素(钾钠钙镁硅硼锂锶砷铁和硫酸根)的分析方法。使用双向观测模式可确保不同浓度元素的同时检出,且地热水采用1%硝酸介质保存,在5周时间内11种元素含量的测定值基本稳定。方法检出限为0.0006~0.0162 mg/L,加标回收率为95.5%~105.8%,精密度(RSD,n =10)均小于6%,实际水样的测试结果与传统方法基本吻合。本方法为西藏温泉的水文地球化学研究提供了大量可靠的数据。
西藏地熱水的礦化度普遍較高,礦物質種類豐富,本文建立瞭採用電感耦閤等離子體髮射光譜(ICP -OES)同時測定西藏日多溫泉地熱水中11種主次量元素(鉀鈉鈣鎂硅硼鋰鍶砷鐵和硫痠根)的分析方法。使用雙嚮觀測模式可確保不同濃度元素的同時檢齣,且地熱水採用1%硝痠介質保存,在5週時間內11種元素含量的測定值基本穩定。方法檢齣限為0.0006~0.0162 mg/L,加標迴收率為95.5%~105.8%,精密度(RSD,n =10)均小于6%,實際水樣的測試結果與傳統方法基本吻閤。本方法為西藏溫泉的水文地毬化學研究提供瞭大量可靠的數據。
서장지열수적광화도보편교고,광물질충류봉부,본문건립료채용전감우합등리자체발사광보(ICP -OES)동시측정서장일다온천지열수중11충주차량원소(갑납개미규붕리송신철화류산근)적분석방법。사용쌍향관측모식가학보불동농도원소적동시검출,차지열수채용1%초산개질보존,재5주시간내11충원소함량적측정치기본은정。방법검출한위0.0006~0.0162 mg/L,가표회수솔위95.5%~105.8%,정밀도(RSD,n =10)균소우6%,실제수양적측시결과여전통방법기본문합。본방법위서장온천적수문지구화학연구제공료대량가고적수거。
Geothermal water in Tibet has a high degree of mineralization with abundant mineral substances. Simultaneous determination of potassium,sodium,calcium,magnesium,silicon,boron,lithium,strontium, arsenic,iron and sulfate radical in geothermal water of Riduo Hotspring by Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES)was developed in this study.Analytical conditions were optimized by application of two-way observation mode to ensure simultaneous determination of the multi-elements in geothermal water.In addition,geothermal water was preserved in 1 % nitric acid and the results of 11 elements after five weeks are stable.This method has a detection limit of 0.0006 -0.0162 mg/L,recoveries of 95.5% -105.8% by standard addition,and relative standard deviation (RSD,n =10)of less than 6%.The analytical results were in good agreement with those obtained by traditional methods.This method provides a number of reliable data for hydrogeochemical research on geothermal water in Tibet.