化工学报
化工學報
화공학보
JOURNAL OF CHEMICAL INDUSY AND ENGINEERING (CHINA)
2015年
6期
2011-2016
,共6页
章学来%刘田田%赵群志%梁笑阳%徐蔚雯
章學來%劉田田%趙群誌%樑笑暘%徐蔚雯
장학래%류전전%조군지%량소양%서위문
过冷度%多孔介质%统计方法%热导率
過冷度%多孔介質%統計方法%熱導率
과랭도%다공개질%통계방법%열도솔
supercooling degree%porous media%statistical methods%thermal conductivity
为研究多孔球层的存在对水过冷的影响,采用不同材料(铝、不锈钢、玻璃)和不同球径(5、8、11 mm)的多孔球层固体基底进行了实验研究。由于水的过冷度并非一定值,因此进行多次实验并采用统计方法进行分析。实验结果表明:多孔球层内蒸馏水的过冷度分布比纯蒸馏水分布更集中,且过冷度值比纯蒸馏水小;同材质不同球径多孔球层内水的平均过冷度整体上随着球径减小而减小;固体基底的热导率越大,多孔球层内水的过冷度分布越集中且平均过冷度也越小;固体基底的热导率较小时,易壁面成核,沿壁面由外向内缓慢结晶,相变时间明显多于均匀成核,而均匀成核一旦形成晶核,晶核就会瞬间长大,形成的冰疏松,因此工程应用中应尽量避免壁面成核。
為研究多孔毬層的存在對水過冷的影響,採用不同材料(鋁、不鏽鋼、玻璃)和不同毬徑(5、8、11 mm)的多孔毬層固體基底進行瞭實驗研究。由于水的過冷度併非一定值,因此進行多次實驗併採用統計方法進行分析。實驗結果錶明:多孔毬層內蒸餾水的過冷度分佈比純蒸餾水分佈更集中,且過冷度值比純蒸餾水小;同材質不同毬徑多孔毬層內水的平均過冷度整體上隨著毬徑減小而減小;固體基底的熱導率越大,多孔毬層內水的過冷度分佈越集中且平均過冷度也越小;固體基底的熱導率較小時,易壁麵成覈,沿壁麵由外嚮內緩慢結晶,相變時間明顯多于均勻成覈,而均勻成覈一旦形成晶覈,晶覈就會瞬間長大,形成的冰疏鬆,因此工程應用中應儘量避免壁麵成覈。
위연구다공구층적존재대수과랭적영향,채용불동재료(려、불수강、파리)화불동구경(5、8、11 mm)적다공구층고체기저진행료실험연구。유우수적과랭도병비일정치,인차진행다차실험병채용통계방법진행분석。실험결과표명:다공구층내증류수적과랭도분포비순증류수분포경집중,차과랭도치비순증류수소;동재질불동구경다공구층내수적평균과랭도정체상수착구경감소이감소;고체기저적열도솔월대,다공구층내수적과랭도분포월집중차평균과랭도야월소;고체기저적열도솔교소시,역벽면성핵,연벽면유외향내완만결정,상변시간명현다우균균성핵,이균균성핵일단형성정핵,정핵취회순간장대,형성적빙소송,인차공정응용중응진량피면벽면성핵。
In order to study the effects of bead-packed porous structure, balls of different materials such as aluminum, stainless steel and glass with different diameters of 5, 8 and 11 mm are added into distilled water forming porous media. Since the supercooling degree of water is not a certain value, the experiments are repeated many times at the same cooling condition and analyzed with statistical methods. The results show that the distribution of the supercooling degree of distilled water in porous media is more concentrated than that of pure distilled water and the supercooling degree of water in porous media is smaller. The average supercooling degree of distilled water decreases with decreasing diameter of the same material balls on the whole. The larger the thermal conductivity of solid substrate is, the more concentrated the distribution of supercooling degree of distilled water in porous media and the smaller the average supercooling degree. In addition, the heterogeneous nucleation is more likely to occur when the thermal conductivity of the solid substrate is small. An annulus solid ice begins to grow slowly from the inside wall to the center region and the phase change time is longer than homogeneous nucleation. Once the crystal nucleus is formed, it will grow up instantly, forming the loose ice of homogeneous nucleation. Therefore, the heterogeneous nucleation should be avoided in engineering application.