物探与化探
物探與化探
물탐여화탐
GEOPHYSICAL AND GEOCHEMICAL EXPLORATION
2015年
3期
595-601,605
,共8页
吴雪芳%岑况%赵伦山%刘秀丽%史瑾瑾%朱雪涛
吳雪芳%岑況%趙倫山%劉秀麗%史瑾瑾%硃雪濤
오설방%잠황%조륜산%류수려%사근근%주설도
土壤重金属%生态地球化学%来源识别%顺德
土壤重金屬%生態地毬化學%來源識彆%順德
토양중금속%생태지구화학%래원식별%순덕
soil heavy metal%ecological geochemistry%source recognition%Shunde area
通过对广东省顺德地区土壤进行1∶5万生态地球化学详查,探讨了该区土壤重金属的来源,并对土壤重金属污染现状作了初步评价。对测区495个样品的测试数据统计分析发现,土壤中 Cd、Cu、Pb、Zn、As 和 Hg 含量都明显超出广东省土壤均值,Cd 和 As 分别高出18和6.8倍。根据土地利用方式,将研究区按土地功能分成河道沿岸、工厂用地(包括家具厂和电器厂)、鱼塘基土、居民区四类,计算不同功能区土壤单因子污染指数(Pi )和内梅罗综合指数(P综),重金属平均污染程度为 Cd>As>Zn>Cu>Hg>Pb,综合污染指数大小为河道沿岸>家具厂区>居民区>鱼塘基地>电器厂区土。对研究区水样和蔬菜样的分析可知,研究区土—水—植物已全面受到污染。利用 Pearson 相关分析和主成分分析,Cd、Cu、Pb、Zn 相关性高,是典型的铅锌矿组合,主要受自然因素控制,为自然三角洲沉积;As不仅由河流带来,也由工业活动释放出;Hg 主要来自人类生活区的各种废弃物堆放。结合土壤自然形态和土地利用类型判断,测区土壤重金属的严重污染和癌症等水土病的高发性,是自然沉积富集和人为工业污染相叠加的两种作用的结果。
通過對廣東省順德地區土壤進行1∶5萬生態地毬化學詳查,探討瞭該區土壤重金屬的來源,併對土壤重金屬汙染現狀作瞭初步評價。對測區495箇樣品的測試數據統計分析髮現,土壤中 Cd、Cu、Pb、Zn、As 和 Hg 含量都明顯超齣廣東省土壤均值,Cd 和 As 分彆高齣18和6.8倍。根據土地利用方式,將研究區按土地功能分成河道沿岸、工廠用地(包括傢具廠和電器廠)、魚塘基土、居民區四類,計算不同功能區土壤單因子汙染指數(Pi )和內梅囉綜閤指數(P綜),重金屬平均汙染程度為 Cd>As>Zn>Cu>Hg>Pb,綜閤汙染指數大小為河道沿岸>傢具廠區>居民區>魚塘基地>電器廠區土。對研究區水樣和蔬菜樣的分析可知,研究區土—水—植物已全麵受到汙染。利用 Pearson 相關分析和主成分分析,Cd、Cu、Pb、Zn 相關性高,是典型的鉛鋅礦組閤,主要受自然因素控製,為自然三角洲沉積;As不僅由河流帶來,也由工業活動釋放齣;Hg 主要來自人類生活區的各種廢棄物堆放。結閤土壤自然形態和土地利用類型判斷,測區土壤重金屬的嚴重汙染和癌癥等水土病的高髮性,是自然沉積富集和人為工業汙染相疊加的兩種作用的結果。
통과대광동성순덕지구토양진행1∶5만생태지구화학상사,탐토료해구토양중금속적래원,병대토양중금속오염현상작료초보평개。대측구495개양품적측시수거통계분석발현,토양중 Cd、Cu、Pb、Zn、As 화 Hg 함량도명현초출광동성토양균치,Cd 화 As 분별고출18화6.8배。근거토지이용방식,장연구구안토지공능분성하도연안、공엄용지(포괄가구엄화전기엄)、어당기토、거민구사류,계산불동공능구토양단인자오염지수(Pi )화내매라종합지수(P종),중금속평균오염정도위 Cd>As>Zn>Cu>Hg>Pb,종합오염지수대소위하도연안>가구엄구>거민구>어당기지>전기엄구토。대연구구수양화소채양적분석가지,연구구토—수—식물이전면수도오염。이용 Pearson 상관분석화주성분분석,Cd、Cu、Pb、Zn 상관성고,시전형적연자광조합,주요수자연인소공제,위자연삼각주침적;As불부유하류대래,야유공업활동석방출;Hg 주요래자인류생활구적각충폐기물퇴방。결합토양자연형태화토지이용류형판단,측구토양중금속적엄중오염화암증등수토병적고발성,시자연침적부집화인위공업오염상첩가적량충작용적결과。
Soil survey was conducted in Shunde area with the method of 1 ∶50 000 ecological geochemistry detailed survey to evaluate the source and the current status of heavy metal contamination in soils. A total of 495 samples of soil were collected from Shunde area.The statistical analysis shows that the levels of Cd, Cu, Pb, Zn, As and Hg are obviously higher than their soil average threshold values in Guangdong, implying heavy pollution. The mean values of heavy metals in soil samples exceed the corresponding back?ground values in Guangdong Province. The mean values of Cd and As are 18 and 6.8 times, respectively, as high as the soil back?ground values. According to different determinations, we divided the study area into four parts: river way, industrial soil (including furniture factory and electric appliance), fishpond land and residential area. The pollution index (Pi ) of each metal and the Nemer?ow integrated pollution index (P综) were calculated in the different functional zones. The pollution degree is in order of Cd>As>Zn>Cu>Hg>Pb. The Nemerow integrated pollution indexes of the different areas are in order of river way > furniture factory > residential area > fishpond > electric appliance. Combined with the study of water and vegetables in Shunde area, the authors have revealed that the soil?water?plant system has been contaminated. Using the Pearson??s correlation coefficient and the principal component analysis, the authors have found that there is a significant positive correlation between Cd, Cu, Pb and Zn, which constitute a typical combi?nation of the lead?zinc mine and suggest a delta deposit controlled by natural factors. As comes not only from the river but also from the industrial activity; Hg is mainly derived from anthropogenic source. Combined with the natural mode of occurrence of soil and land?use type, the authors can judge the source of heavy metal in the study area. It is held that the serious contamination of heavy metals and the high adaptive disease in the study area originate from natural depositition and anthropogenic sources.