广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2015年
10期
53-54,72
,共3页
沈天涵%谢岁岁%嵇凤玲%李晶晶%杜飞鹏
瀋天涵%謝歲歲%嵇鳳玲%李晶晶%杜飛鵬
침천함%사세세%혜봉령%리정정%두비붕
聚苯胺%多壁碳纳米管%复合材料%热电性能
聚苯胺%多壁碳納米管%複閤材料%熱電性能
취분알%다벽탄납미관%복합재료%열전성능
polyaniline%multi-walled carbon nanotubes%nanocomposites%thermoelectric properties
通过原位聚合,将聚苯胺接枝到多壁碳纳米管的表面,制备了聚苯胺/碳纳米管纳米纤维。聚苯胺均匀地包覆在碳纳米管表面,当苯胺与碳纳米管投料比为11时,包覆层厚度约为15 nm。聚苯胺/多壁碳纳米管的电导率和塞贝克系数随温度升高而增大,且增大碳纳米管含量同时提高了复合材料的电导率和塞贝克系数,改善了功率因子。
通過原位聚閤,將聚苯胺接枝到多壁碳納米管的錶麵,製備瞭聚苯胺/碳納米管納米纖維。聚苯胺均勻地包覆在碳納米管錶麵,噹苯胺與碳納米管投料比為11時,包覆層厚度約為15 nm。聚苯胺/多壁碳納米管的電導率和塞貝剋繫數隨溫度升高而增大,且增大碳納米管含量同時提高瞭複閤材料的電導率和塞貝剋繫數,改善瞭功率因子。
통과원위취합,장취분알접지도다벽탄납미관적표면,제비료취분알/탄납미관납미섬유。취분알균균지포복재탄납미관표면,당분알여탄납미관투료비위11시,포복층후도약위15 nm。취분알/다벽탄납미관적전도솔화새패극계수수온도승고이증대,차증대탄납미관함량동시제고료복합재료적전도솔화새패극계수,개선료공솔인자。
PANi was grafted onto the surface of multi - walled carbon nanotubes ( MWNTs ) by in - situ polymerization. Transmission electron microscopy showed that PANi can be evenly coated on the surface of MWNTs and the layer thickness was about 15 nm when the ratio of aniline and the MWNTs was 11. The testings of thermoelectric properties showed electrical conductivity and seebeck coefficient of PANi/MWNTs both increased with the temperature increased and the increase content of MWNTs. The power factors were both greatly improved.