CAJ | 학술논문

目的了解江汉平原地方性砷中毒(地砷病)病区地下水砷含量变化,探讨该区域高砷水赋存环境、地下水系统砷的来源.方法在湖北省仙桃市和洪湖市分别以地砷病患者家为中心点,在3km半径内各采集30份地下水样品和3个地质钻孔沉积物样芯;水砷含量比较采用配对t检验或配对符号秩和检验进行分析.结果仙桃市南洪村2011-2012年水砷浓度低于2006-2007年(t=4.645 3,P＜0.000 1),洪湖市姚河村2011-2012年水砷浓度高于2006-2007年(S=-150,P＜0.000 1);高砷水呈弱酸、弱氧化性,水砷浓度与水样C1-、HCO3-、Fe、Mn浓度正相关,与水样SO42-、NO3-浓度负相关;研究区沉积物中砷浓度为1.500～ 17.289mg/kg,砷含量最大值均出现在泥土层,最小值均出现在沙层.结论江汉平原地砷病病区高砷水砷含量的时空间变化程度较大,与中国山西大同盆地、山阴地区、内蒙古河套平原等原生高砷水地区有明显差异,为典型的高砷水赋存环境;研究区沉积物样品中砷含量与岩性结构有密切关系.
목적 료해강한평원지방성신중독(지신병)병구지하수신함량변화,탐토해구역고신수부존배경、지하수계통신적래원.방법 재호북성선도시화홍호시분별이지신병환자가위중심점,재3km반경내각채집30빈지하수양품화3개지질찬공침적물양심;수신함량비교채용배대t검험혹배대부호질화검험진행분석.결과 선도시남홍촌2011-2012년수신농도저우2006-2007년(t=4.645 3,P＜0.000 1),홍호시요하촌2011-2012년수신농도고우2006-2007년(S=-150,P＜0.000 1);고신수정약산、약양화성,수신농도여수양C1-、HCO3-、Fe、Mn농도정상관,여수양SO42-、NO3-농도부상관;연구구침적물중신농도위1.500～ 17.289mg/kg,신함량최대치균출현재니토층,최소치균출현재사층.결론 강한평원지신병병구고신수신함량적시공간변화정도교대,여중국산서대동분지、산음지구、내몽고하투평원등원생고신수지구유명현차이,위전형적고신수부존배경;연구구침적물양품중신함량여암성결구유밀절관계.
Objective To understand the variation of arsenic concentration in underground water at the endemic arsenic poison disease area of Jianghan Plain so as to better understand the spatial distribution of high arsenic groundwater,hydro-chemical evolution and source of arsenic in this region.Methods Thirty underground water samples were collected respectively around 3 km radius of the two houses where arsenic poisoning patients lived,in Xiantao and Honghu.Sediment cores of three drillings were collected as well.Both paired t-test or paired Wilcoxon Signed Ranking Test were used to compare the arsenic concentration of water.Results The arsenic concentration in 2011-2012 appeared lower than that in 2006-2007 at the Nanhong village of Xiantao (t=4.645 3,P＜0.000 1),but was higher(S=-150,P＜0.000 1) in the Yaohe village of Honghu.The pH value showed weak acidity with Eh as weak oxidated.Positive correlations were observed between arsenic concentration and C1,HCO3-,Fe,Mn.However,negative correlations were found between As and SO42-,NO3-.The range of arsenic content in the sediment was 1.500 mg/kg to 17.289 mg/kg.The maximum arsenic content existed in the soil layer,while the minimum arsenic content existed in the sand layer.Conclusion The concentration of arsenic varied widely with time and space at endemic arsenic poison disease area of Jianghan Plain.Characteristics of these water chemicals showed significant differences,when compared to the groundwater from Datong Basin,Shanxi Shanyin and Hetao Plain of Inner Mongolia,which presented a typical environment with high arsenic contents in the groundwater.The arsenic content in the sediment samples seemed related to the lithologic structure.