燃烧科学与技术
燃燒科學與技術
연소과학여기술
JOURNAL OF COMBUSTION SCIENCE AND TECHNOLOGY
2015年
3期
229-235
,共7页
江洋%张会岩%邵珊珊%肖睿
江洋%張會巖%邵珊珊%肖睿
강양%장회암%소산산%초예
生物质%烘焙预处理%裂解气相色谱质谱联用%催化热解
生物質%烘焙預處理%裂解氣相色譜質譜聯用%催化熱解
생물질%홍배예처리%렬해기상색보질보련용%최화열해
biomass%torrefaction pretreatment%PY-GC/MS%catalytic pyrolysis
在管式炉中对木屑进行烘焙,对其产物进行热解和催化热解研究。考察了不同温度下烘焙挥发物析出特性以及烘焙预处理对生物质热解的影响,重点比较了烘焙后乙酸、愈创木酚类和芳烃催化热解产率的变化规律。结果表明,烘焙温度为250,℃时,在HZSM-5催化剂作用下能有效改善热解产物的选择性,甲苯和二甲苯产率达到未烘焙生物质的近2倍,而乙酸和大部分愈创木酚类产物的产率较原生物质催化热解产率有明显降低。
在管式爐中對木屑進行烘焙,對其產物進行熱解和催化熱解研究。攷察瞭不同溫度下烘焙揮髮物析齣特性以及烘焙預處理對生物質熱解的影響,重點比較瞭烘焙後乙痠、愈創木酚類和芳烴催化熱解產率的變化規律。結果錶明,烘焙溫度為250,℃時,在HZSM-5催化劑作用下能有效改善熱解產物的選擇性,甲苯和二甲苯產率達到未烘焙生物質的近2倍,而乙痠和大部分愈創木酚類產物的產率較原生物質催化熱解產率有明顯降低。
재관식로중대목설진행홍배,대기산물진행열해화최화열해연구。고찰료불동온도하홍배휘발물석출특성이급홍배예처리대생물질열해적영향,중점비교료홍배후을산、유창목분류화방경최화열해산솔적변화규률。결과표명,홍배온도위250,℃시,재HZSM-5최화제작용하능유효개선열해산물적선택성,갑분화이갑분산솔체도미홍배생물질적근2배,이을산화대부분유창목분류산물적산솔교원생물질최화열해산솔유명현강저。
Sawdust pretreatment of torrefaction followed by the pyrolysis or catalytic pyrolysis of its productwas conducted in a tube furnace. The effects of torrefaction temperature on vapor distributions and product distributions of pyrolysis were studied. The yields of acetic acid,guaiacols and aromatics before and after torrefaction were com-pared. The results show that the selectivity of pyrolysis products can be effectively improved when the torrefaction temperature is 250,℃ with HZSM-5 catalyst. The yields of toluene and xylene are nearly twice that with original biomass,while the yields of acetic acid and guaiacols decrease obviouslycompared with that with original biomass in catalytic pyrolysis process.