CAJ | 학술논문

以4-氰基吡啶和盐酸胍为原料通过关环反应得到了一种新的有机化合物,2-氨基-4,6-二(4-吡啶基)-l,3,5-三嗪(4-HABPT)并得到了其单晶结构(4-HABPT·CH 3 CN,1),通过单晶结构分析、元素分析和红外分析法对化合物1的结构进行了表征．单晶结构表明,化合物1属于正交晶系的 Cmc 21空间群,每个晶胞中含0．5个4-HABPT 分子和0．5个乙腈分子．4-HABPT 分子之间通过氨基与吡啶环上 N 原子之间的氢键连接形成处于 ab 平面的有序的二维氢键网络结构,层与层之间再通过π…π作用以及弱的 C-H…N 氢键连接形成三维结构．
이4-청기필정화염산고위원료통과관배반응득도료일충신적유궤화합물,2-안기-4,6-이(4-필정기)-l,3,5-삼진(4-HABPT)병득도료기단정결구(4-HABPT·CH 3 CN,1),통과단정결구분석、원소분석화홍외분석법대화합물1적결구진행료표정．단정결구표명,화합물1속우정교정계적 Cmc 21공간군,매개정포중함0．5개4-HABPT 분자화0．5개을정분자．4-HABPT 분자지간통과안기여필정배상 N 원자지간적경건련접형성처우 ab 평면적유서적이유경건망락결구,층여층지간재통과π…π작용이급약적 C-H…N 경건련접형성삼유결구．
An organic compound 2-amino-4,6-bis(4-pyridyl)-l,3,5-triazine(4-HABPT)was synthesized by using 4-cyanopyridine and guanidine hydrochloride as raw materials,whose single crystal structure 4-HABPT · CH 3 CN (1 ) was also determined.Single-crystal X-ray diffraction analyses indicate that compound 1 crystallizes in the orthorhombic Cmc 2 1 space group,and contains 0.5 4-HABPT molecule and 0.5 CH 3 CN molecule in an asymmetric unit.The 4-HABPT molecules formed 2D hydrogen-bonding layers via hydrogen bondings between the amino groups and N atoms of pyridyl groups firstly,and then linked to 3D structure viaπ…π interaction between triazine rings and weak hydrogen bondings of C-H…N between the 2D frameworks and solvent molecules.