天然气化工（C1化学与化工）
天然氣化工（C1化學與化工）
천연기화공（C1화학여화공）
Natural Gas Chemical Industry
2015年
3期
10-12,44
,共4页
李军%赖崇伟%王莉%周拥华
李軍%賴崇偉%王莉%週擁華
리군%뢰숭위%왕리%주옹화
环氧丙烷%TS-1分子筛%丙烯%过氧化氢%溶剂影响
環氧丙烷%TS-1分子篩%丙烯%過氧化氫%溶劑影響
배양병완%TS-1분자사%병희%과양화경%용제영향
propylene oxide%TS-1 zeolite%propylene%hydrogen peroxide%solvent effect
制备了丙烯环氧化制环氧丙烷TS-1分子筛催化剂，并对影响TS-1分子筛催化活性的因素进行了研究。结果表明，制备TS-1分子筛催化剂最佳硅源为正硅酸乙酯，最佳钛源为钛酸异丁酯，最佳催化剂焙烧温度和焙烧时间分别为540℃和8h。同时考察了甲醇和异丙醇溶剂对丙烯环氧化制环氧丙烷反应的影响，结果显示甲醇能更好地提高催化剂活性。
製備瞭丙烯環氧化製環氧丙烷TS-1分子篩催化劑，併對影響TS-1分子篩催化活性的因素進行瞭研究。結果錶明，製備TS-1分子篩催化劑最佳硅源為正硅痠乙酯，最佳鈦源為鈦痠異丁酯，最佳催化劑焙燒溫度和焙燒時間分彆為540℃和8h。同時攷察瞭甲醇和異丙醇溶劑對丙烯環氧化製環氧丙烷反應的影響，結果顯示甲醇能更好地提高催化劑活性。
제비료병희배양화제배양병완TS-1분자사최화제，병대영향TS-1분자사최화활성적인소진행료연구。결과표명，제비TS-1분자사최화제최가규원위정규산을지，최가태원위태산이정지，최가최화제배소온도화배소시간분별위540℃화8h。동시고찰료갑순화이병순용제대병희배양화제배양병완반응적영향，결과현시갑순능경호지제고최화제활성。
TS-1 zeolite catalysts for preparation of propylene oxide by epoxidation of propylene using hydrogen peroxide were synthesized, and the effects of preparation conditions on the performances of catalyst were investigated. The results showed that the optimum Si source and Ti source were tetraethoxysilane and tetraisobutyl orthotitanate, respectively, and the optimum calcination temperature and time were 540℃ and 8 hours, respectively. Furthermore, the effects of methanol and isopropanol solvents on the reaction were also studied, and it was found that methanol could improve the activity of catalyst much more.
