化工时刊
化工時刊
화공시간
CHEMICAL INDUSTRY TIMES
2015年
3期
12-13,21
,共3页
王晓兰%王建军%范妮%张静%倪俊超%陈经涛
王曉蘭%王建軍%範妮%張靜%倪俊超%陳經濤
왕효란%왕건군%범니%장정%예준초%진경도
(%n-C12%H25%NH3%)%2%CdCl4%(%s)%晶格能量%溶解-反应热量计%标准摩尔生成焓
(%n-C12%H25%NH3%)%2%CdCl4%(%s)%晶格能量%溶解-反應熱量計%標準摩爾生成焓
(%n-C12%H25%NH3%)%2%CdCl4%(%s)%정격능량%용해-반응열량계%표준마이생성함
(n-C12H25NH3)2 CdCl4(s) lattice energy solution reaction calorimeter standard molar en-thalpy of formation
用水热合成法合成了晶体化合物 (n-C12H25NH3)2 CdCl4(s);根据热化学原理计算了化合物(n-C12H25 NH3)2 CdCl4(s)的晶格能为889. 81 kJ·mol-1. 利用等温溶解-反应热量计,得到了该化合物的标准的摩尔焓: [(n-C12H25NH3)2 CdCl4,s] = -(1836.23 ±7.95) kJ·mol-1.
用水熱閤成法閤成瞭晶體化閤物 (n-C12H25NH3)2 CdCl4(s);根據熱化學原理計算瞭化閤物(n-C12H25 NH3)2 CdCl4(s)的晶格能為889. 81 kJ·mol-1. 利用等溫溶解-反應熱量計,得到瞭該化閤物的標準的摩爾焓: [(n-C12H25NH3)2 CdCl4,s] = -(1836.23 ±7.95) kJ·mol-1.
용수열합성법합성료정체화합물 (n-C12H25NH3)2 CdCl4(s);근거열화학원리계산료화합물(n-C12H25 NH3)2 CdCl4(s)적정격능위889. 81 kJ·mol-1. 이용등온용해-반응열량계,득도료해화합물적표준적마이함: [(n-C12H25NH3)2 CdCl4,s] = -(1836.23 ±7.95) kJ·mol-1.
The crystal compounds synthesized by the hydrothermal synthesis of (n-C12H25NH3)2 CdCl4(s);compound were calculated based on the thermochemical principle ( n-C12 H25 NH3 ) 2 CdCl4 ( s) of the lattice energy of 889. 81 kJ·mol-1 . Using isothermal solution reaction calorimeter,the standard molar enthalpy of the compound was obtained:[n-C12H25NH3)2 CdCl4,S] = - (1 836. 23 + 7. 95) kJ David mol-1.
