化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2015年
7期
1956-1961
,共6页
刘盛%朱红祥%王进%刘晨%孔巧平%曹雪娟
劉盛%硃紅祥%王進%劉晨%孔巧平%曹雪娟
류성%주홍상%왕진%류신%공교평%조설연
壳聚糖%黄原酸化壳聚糖%超声波%辐射%合成%多相反应
殼聚糖%黃原痠化殼聚糖%超聲波%輻射%閤成%多相反應
각취당%황원산화각취당%초성파%복사%합성%다상반응
chitosan%xanthation chitosan%ultrasonic%radiation%synthesis%multiphase reaction
介绍了制备黄原酸化壳聚糖（XCTS）的常规方法和超声波法，使用元素分析、FT-IR、XRD、SEM 和 TG对其结构进行表征，并分析了物料比、超声波功率、反应温度、反应时间和碱浓度对超声波法制备 XCTS 的影响。结果表明超声波法能明显加快制备黄原酸化壳聚糖的速度，增加产量，同时提高产物的硫含量，其最佳工艺：壳聚糖与二硫化碳的质量体积比为1∶2（g/mL），超声波功率为150W，超声波作用时间为60min，NaOH的质量分数为15%。
介紹瞭製備黃原痠化殼聚糖（XCTS）的常規方法和超聲波法，使用元素分析、FT-IR、XRD、SEM 和 TG對其結構進行錶徵，併分析瞭物料比、超聲波功率、反應溫度、反應時間和堿濃度對超聲波法製備 XCTS 的影響。結果錶明超聲波法能明顯加快製備黃原痠化殼聚糖的速度，增加產量，同時提高產物的硫含量，其最佳工藝：殼聚糖與二硫化碳的質量體積比為1∶2（g/mL），超聲波功率為150W，超聲波作用時間為60min，NaOH的質量分數為15%。
개소료제비황원산화각취당（XCTS）적상규방법화초성파법，사용원소분석、FT-IR、XRD、SEM 화 TG대기결구진행표정，병분석료물료비、초성파공솔、반응온도、반응시간화감농도대초성파법제비 XCTS 적영향。결과표명초성파법능명현가쾌제비황원산화각취당적속도，증가산량，동시제고산물적류함량，기최가공예：각취당여이류화탄적질량체적비위1∶2（g/mL），초성파공솔위150W，초성파작용시간위60min，NaOH적질량분수위15%。
This paper described the preparation of xanthation chitosan (XCTS) by the conventional and ultrasonic methods. The elemental analysis,FT-IR,XRD,SEM and TG were adopted to characterize the structure of the products. In addition,the effects of material ratio,ultrasonic power,reaction temperature,reaction time and alkali concentration on the prepared XCTS were studied. The results showed that ultrasonic method could significantly speed up the preparation process and increase its production,as well as increasing the sulfur content of products. The optimum conditions for preparation were as follows:the mass ratio of chitosan to carbon disulfide was 1∶2; the ultrasonic power was 150W; the ultrasonic time was 60min,and NaOH solution was of 15%.
