CAJ | 학술논문

以过硫酸铵为引发剂，双氧水为氧化剂，冰乙酸为溶剂，将2‐甲基萘氧化为2‐甲萘醌，进而制得亚硫酸氢钠甲萘醌．研究了反应时间、反应温度、引发剂的用量及反应物与氧化剂、溶剂的物料比等因素对产品收率的影响．确定了最佳的反应条件是2‐甲萘醌的合成条件为：反应时间3 h ，反应温度85℃，引发剂的用量为反应物总量的2％，n（2‐甲基萘）∶ n（冰乙酸）∶ n （双氧水）＝1∶15∶11．5．亚硫酸氢钠甲萘醌的合成条件为：反应温度45℃，反应时间1 h ，n （2‐甲萘醌）∶ n（亚硫酸氢钠）＝1∶1．5．在以上条件下，2‐甲萘醌的收率为54％，亚硫酸氢钠甲萘醌的收率为70％．
이과류산안위인발제，쌍양수위양화제，빙을산위용제，장2‐갑기내양화위2‐갑내곤，진이제득아류산경납갑내곤．연구료반응시간、반응온도、인발제적용량급반응물여양화제、용제적물료비등인소대산품수솔적영향．학정료최가적반응조건시2‐갑내곤적합성조건위：반응시간3 h ，반응온도85℃，인발제적용량위반응물총량적2％，n（2‐갑기내）∶ n（빙을산）∶ n （쌍양수）＝1∶15∶11．5．아류산경납갑내곤적합성조건위：반응온도45℃，반응시간1 h ，n （2‐갑내곤）∶ n（아류산경납）＝1∶1．5．재이상조건하，2‐갑내곤적수솔위54％，아류산경납갑내곤적수솔위70％．
Synthesis of 2‐methylnaphthoquinone with ammonium persulfate as initiator in the acetic‐H202 system by oxidation of 2‐methylnaphthalene was researched .The effects of reac‐tion temperature ,reaction time ,amount of initiator ,reactant and solvent material ratio and other factors on β‐methylnaphthoquinone yeild were investigated .The best performences were achieved .The synthesis conditions of 2‐methylnaphthoquinone:reaction time 3 h ,reac‐tion temperature 85 ℃ ,molar ratio of 2‐methylnaphthalene to acetic acid and Hydrogen per‐oxide 1∶11 .5∶15 ,amoout of initiator is 2% of the total amount of reactant .The synthesis conditions of menadione sodium bisulfite:reaction time 1 h ,reaction temperature 45 ℃ ,molar ratio of 2‐methylnaphthoquinone to sodium bisulfite 1∶1 .5 .In these conditions ,the yelid of 2‐methylnaphthoquinone was 54% ,the yelid of menadione sodium bisulfite was 70% .