应用化工
應用化工
응용화공
APPLIED CHEMICAL INDUSTRY
2015年
6期
986-990,999
,共6页
徐秀林%吴卫红%柳东海%郑成航%施正伦%高翔
徐秀林%吳衛紅%柳東海%鄭成航%施正倫%高翔
서수림%오위홍%류동해%정성항%시정륜%고상
催化剂%磨损率%端面%孔壁%数值模拟
催化劑%磨損率%耑麵%孔壁%數值模擬
최화제%마손솔%단면%공벽%수치모의
catalyst%erosion rate%pore wall%hole wall%numerical simulating
催化剂磨损是引起SCR催化剂失效的主要原因之一。基于计算流体力学软件对催化剂端面和孔壁磨损进行数值模拟研究,讨论了催化剂孔径大小、多层布置间距、孔道堵塞对催化剂磨损的影响。结果表明,催化剂孔径大小对催化剂端面磨损率影响不大,与孔壁磨损率呈反比;催化剂多层布置时,第二层催化剂的端面磨损率随布置间距的增加先增加后保持不变,而孔壁磨损率先减小后维持不变;当催化剂孔道堵塞时,堵塞孔附近孔的外壁面磨损加剧,导致孔壁磨损率明显增加,而端面磨损率变化不大,因此在工程实际运行中,应避免催化剂的堵塞。
催化劑磨損是引起SCR催化劑失效的主要原因之一。基于計算流體力學軟件對催化劑耑麵和孔壁磨損進行數值模擬研究,討論瞭催化劑孔徑大小、多層佈置間距、孔道堵塞對催化劑磨損的影響。結果錶明,催化劑孔徑大小對催化劑耑麵磨損率影響不大,與孔壁磨損率呈反比;催化劑多層佈置時,第二層催化劑的耑麵磨損率隨佈置間距的增加先增加後保持不變,而孔壁磨損率先減小後維持不變;噹催化劑孔道堵塞時,堵塞孔附近孔的外壁麵磨損加劇,導緻孔壁磨損率明顯增加,而耑麵磨損率變化不大,因此在工程實際運行中,應避免催化劑的堵塞。
최화제마손시인기SCR최화제실효적주요원인지일。기우계산류체역학연건대최화제단면화공벽마손진행수치모의연구,토론료최화제공경대소、다층포치간거、공도도새대최화제마손적영향。결과표명,최화제공경대소대최화제단면마손솔영향불대,여공벽마손솔정반비;최화제다층포치시,제이층최화제적단면마손솔수포치간거적증가선증가후보지불변,이공벽마손솔선감소후유지불변;당최화제공도도새시,도새공부근공적외벽면마손가극,도치공벽마손솔명현증가,이단면마손솔변화불대,인차재공정실제운행중,응피면최화제적도새。
Catalyst erosion is one of the most important influence factors of SCR catalyst failure. Adopts computational fluid dynamic methods to simulates the erosion at the catalyst front and pore wall,and dis-cuss the catalyst pore size,layer spacing,pore blockage effect on catalyst erosion. The investigation shows that the catalyst pore size has little effect on the catalyst front erosion rate but is inversely proportional to pore wall erosion rate;when catalysts is multilayer arrangement,the second layer catalyst front erosion rate is increased with the layer space increasing at first,then remains unchanged,while the pore wall erosion rate is decreased at first then remains unchanged;When the catalyst pore clogging,outer wall erosion rate around plugging hole is intensified,causing the whole catalyst rate increased,while the catalyst front ero-sion rate changed little;so,it should avoid catalyst blocking in the actual engineering operation.