CAJ | 학술논문

用叠氮硝胺（DIANP）替换硝基胍（NQ）发射药中部分（质量分数6％）硝化甘油（NG）制备了一种含叠氮硝胺的硝基胍发射药。通过高压差示扫描量热法、爆发点试验、甲基紫试验、真空安定性试验和热加速老化试验研究了 DIANP 对 NQ 发射药热行为的影响，用 Kissinger 方程和 Ozawa 方程计算了发射药样品分解反应的表观活化能（Ea ）。结果表明，少量 DIANP 使 NQ 发射药的热安定性稍有改善；Kissinger 方程和 Ozawa 方程计算 NQ 发射药的 Ea 值分别为327和318 kJ／mol，含 DIANP 的 NQ 发射药的 Ea 值分别为196和194 kJ／mol，两者的等动力学点（Tik ）为172．9℃，表明 DIANP 能够降低 NQ 发射药高温下的分解反应速率，即 DIANP 在一定程度上可以调节 NQ发射药的燃速。根据温度系数法预估的含 DIANP 的 NQ 发射药和 NQ 发射药在30℃下的安全贮存寿命分别不少于31年和23年，表明加入少量 DIANP 可延长 NQ 发射药的安全贮存寿命。
용첩담초알（DIANP）체환초기고（NQ）발사약중부분（질량분수6％）초화감유（NG）제비료일충함첩담초알적초기고발사약。통과고압차시소묘량열법、폭발점시험、갑기자시험、진공안정성시험화열가속노화시험연구료 DIANP 대 NQ 발사약열행위적영향，용 Kissinger 방정화 Ozawa 방정계산료발사약양품분해반응적표관활화능（Ea ）。결과표명，소량 DIANP 사 NQ 발사약적열안정성초유개선；Kissinger 방정화 Ozawa 방정계산 NQ 발사약적 Ea 치분별위327화318 kJ／mol，함 DIANP 적 NQ 발사약적 Ea 치분별위196화194 kJ／mol，량자적등동역학점（Tik ）위172．9℃，표명 DIANP 능구강저 NQ 발사약고온하적분해반응속솔，즉 DIANP 재일정정도상가이조절 NQ발사약적연속。근거온도계수법예고적함 DIANP 적 NQ 발사약화 NQ 발사약재30℃하적안전저존수명분별불소우31년화23년，표명가입소량 DIANP 가연장 NQ 발사약적안전저존수명。
A new gun propellant was prepared via replacing the nitroglycerin (NG)with mass fraction of 6% in the nitroguanidine (NQ)-based gun propellant by 1,5-diazido-3-nitrazapentane (DIANP).The effect of DIANP on the thermal behavior of NQ-based gun propellant was studied by high-pressure differential scanning calorimetry,explo-sion temperature test,methyl violet test,vacuum stability test,and thermal accelerated aging test.The apparent activation energy (Ea )of the decomposition reaction of gun propellant sample was calculated by Kissinger equation and Ozawa equation.The results show that a small amount of DIANP makes the thermal stability of NQ-based gun propellant improve slightly.The Ea values obtained by Kissinger equation and Ozawa equation are 327 and 318 kJ/mol respectively for NQ-based gun propellant with DIANP,196 and 194 kJ/mol respectively for NQ-based gun propel-lant.The Ea value of NQ-based gun propellant with DIANP is much less than that of NQ-based gun propellant.Their iso-kinetic temperature Tik is 172.9℃,showing that the addition of DIANP decreases the decomposition rate of NQ-based gun propellant at high temperature,the addition of DIANP can adjust the burning rate of NQ-based gun propellant to a certain degree.The safe storage life of NQ-based gun propellant with DIANP and NQ-based gun propellant at 30℃ predicted by temperature-factor-method is not less than 31 years and 23 years respectively,revealing that adding a small amount of DIANP can prolong the safe storage life of NQ-based gun propellant.