CAJ | 학술논문

采用浸渍涂覆法制备出MnOx/Ti电催化膜.以MnOx/Ti电催化膜为阳极，以不锈钢网为阴极，构建电催化膜反应器用于催化氧化环己烷制备环己醇和环己酮；考察MnOx/Ti膜材料电化学性能以及膜反应器的不同操作参数对环己烷转化率、环己醇和环己酮选择性的影响.结果表明：MnOx/Ti膜材料的电化学性能相对Ti膜明显增强；当反应物浓度为10 mmol/L、停留时间为34.3 min、电流密度为2.9 mA/cm2时，环己烷转化率达到12.5%，环己醇的选择性为38.7%，环己酮的选择性为50.1%.
채용침지도복법제비출MnOx/Ti전최화막.이MnOx/Ti전최화막위양겁，이불수강망위음겁，구건전최화막반응기용우최화양화배기완제비배기순화배기동；고찰MnOx/Ti막재료전화학성능이급막반응기적불동조작삼수대배기완전화솔、배기순화배기동선택성적영향.결과표명：MnOx/Ti막재료적전화학성능상대Ti막명현증강；당반응물농도위10 mmol/L、정류시간위34.3 min、전류밀도위2.9 mA/cm2시，배기완전화솔체도12.5%，배기순적선택성위38.7%，배기동적선택성위50.1%.
The MnOx/Ti eletrocatalytic membrane was prepared via a dip-coating method. The MnOx/Ti eletrocatalytic mem-brane reactor assembled by the MnOx/Ti eletrocatalytic membrane as the anode and a stainless steel mesh as the cathode was employed for oxidation of cyclohexane to produce cyclohexanone and cyclohexanol. The electro-chemical performance of MnOx/Ti membrane and the effects of the different operation parameters on cyclohexane conversion and selectivity to cyclohexanol and cyclohexanone were investigated. Results indicate that the electro-chemical performance of MnOx/Ti membrane was improved significantly compared with Ti membrane; 12.5 %! conversion of cyclohexane, 38.7%!selectivity to cyclohexanol and 50.1%!selectivity to cyclohexanone were ob-tained under the operating conditions of residence time of 34.3 min, cyclohexane concentration of 10 mmol/L and current density of 2.9 mA/cm2.