粉末冶金材料科学与工程
粉末冶金材料科學與工程
분말야금재료과학여공정
POWDER METALLURGY MATERIALS SCIENCE AND ENGINEERING
2015年
3期
414-418
,共5页
苑硕%唐仁衡%王英%肖志平%卢安贤
苑碩%唐仁衡%王英%肖誌平%盧安賢
원석%당인형%왕영%초지평%로안현
锂离子电池%LiMnPO4%Fe掺杂%固相合成
鋰離子電池%LiMnPO4%Fe摻雜%固相閤成
리리자전지%LiMnPO4%Fe참잡%고상합성
lithium ion battery%LiMnPO4%metal ion doped%solid-state reaction method
以葡萄糖为碳源,对LiH2PO4、MnCO3、FeC2O4与葡萄糖等反应物进行湿法球磨,随后在750℃温度下煅烧,通过固相反应实现对LiMnPO4的铁离子掺杂和碳包覆改性,得到锂离子电池正极材料LiMn1?xFexPO4/C(x=0、0.05、0.10、0.15、0.20)。利用 X 射线衍射(XRD),扫描电镜(SEM)及电化学测试等手段研究铁离子掺杂量对磷酸锰锂的晶体结构、微观形貌与电性能的影响。结果表明,LiMn0.9Fe0.1PO4/C 结晶度良好,颗粒较均匀细小,具有较好的电化学性能,0.05C倍率下的首次放电比容量达到110(mA·h)/g,经过30次循环后,放电比容量约80(mA·h)/g。
以葡萄糖為碳源,對LiH2PO4、MnCO3、FeC2O4與葡萄糖等反應物進行濕法毬磨,隨後在750℃溫度下煅燒,通過固相反應實現對LiMnPO4的鐵離子摻雜和碳包覆改性,得到鋰離子電池正極材料LiMn1?xFexPO4/C(x=0、0.05、0.10、0.15、0.20)。利用 X 射線衍射(XRD),掃描電鏡(SEM)及電化學測試等手段研究鐵離子摻雜量對燐痠錳鋰的晶體結構、微觀形貌與電性能的影響。結果錶明,LiMn0.9Fe0.1PO4/C 結晶度良好,顆粒較均勻細小,具有較好的電化學性能,0.05C倍率下的首次放電比容量達到110(mA·h)/g,經過30次循環後,放電比容量約80(mA·h)/g。
이포도당위탄원,대LiH2PO4、MnCO3、FeC2O4여포도당등반응물진행습법구마,수후재750℃온도하단소,통과고상반응실현대LiMnPO4적철리자참잡화탄포복개성,득도리리자전지정겁재료LiMn1?xFexPO4/C(x=0、0.05、0.10、0.15、0.20)。이용 X 사선연사(XRD),소묘전경(SEM)급전화학측시등수단연구철리자참잡량대린산맹리적정체결구、미관형모여전성능적영향。결과표명,LiMn0.9Fe0.1PO4/C 결정도량호,과립교균균세소,구유교호적전화학성능,0.05C배솔하적수차방전비용량체도110(mA·h)/g,경과30차순배후,방전비용량약80(mA·h)/g。
LiMn1?xFexPO4/C cathode materials for Li-ion battery were synthesized at 750℃ by solid-state reaction method combining with the addition of the glucose as the carbon source and wet ball-milling of reactants. The effects of the doping amount of iron ions on the crystal structure, surface morphology and electrochemical properties of products of LiMn1?xFexPO4/C (x=0, 0.05, 0.10, 0.15, 0.20) were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), electrochemical measurement, respectively. The results indicate that the LiMn0.9Fe0.1PO4/C has the best electrochemical performance, and the initial discharge capacity of the sample reaches approximately 110 (mA·h)/g at 0.05C, moreover the discharge capacity keeps still to 80 (mA·h)/gafter 30 cycles.