CAJ | 학술논문

通过化工流程模拟软件 Aspen Plus 对酯交换法合成碳酸二甲酯(DMC)流程中各塔的主要操作参数进行优化分析，得到该工艺的最佳操作条件。在此基础上，比较选用不同萃取剂苯胺和乙二醇时该工艺流程的热力学效率和 CO2排放量。结果表明，苯胺为萃取剂时，DMC 工艺流程的热力学效率明显提高、能耗降低， CO2排放量也大幅度降低。
통과화공류정모의연건 Aspen Plus 대지교환법합성탄산이갑지(DMC)류정중각탑적주요조작삼수진행우화분석，득도해공예적최가조작조건。재차기출상，비교선용불동췌취제분알화을이순시해공예류정적열역학효솔화 CO2배방량。결과표명，분알위췌취제시，DMC 공예류정적열역학효솔명현제고、능모강저， CO2배방량야대폭도강저。
By optimizing and analyzing parameters of the columns for synthesizing dimethyl carbonate (DMC) by using Aspen Plus software, the optimum operation parameters were obtained. On this basis, the thermodynamic efficiency and CO2 emission of the synthesis process were compared and analyzed when aniline and ethylene glycol were respectively used as extraction agent. The results show that, compared with ethylene glycol as the extraction agent, using aniline as the extraction agent can lead to higher thermodynamic efficiency of DMC process, meanwhile the energy consumption and CO2 emission reduce significantly.