林产化学与工业
林產化學與工業
림산화학여공업
CHEMISTRY AND INDUSTRY OF FOREST PRODUCTS
2015年
3期
38-42
,共5页
霍淑平%吴国民%陈健%刘贵锋%孔振武
霍淑平%吳國民%陳健%劉貴鋒%孔振武
곽숙평%오국민%진건%류귀봉%공진무
腰果酚%环氧稀释剂%固化反应%动态热机械分析
腰果酚%環氧稀釋劑%固化反應%動態熱機械分析
요과분%배양희석제%고화반응%동태열궤계분석
cardanol%epoxy diluent%curing reaction%dynamic mechanical thermal analysis
以天然腰果酚为原料制备了一种高活性腰果酚基环氧稀释剂(CDE),利用所制备的CDE与双酚A型环氧树脂( E-51)共混,再与甲基四氢苯酐进行交联固化反应,通过力学性能测试,研究了稀释剂含量对固化物性能的影响。实验结果表明:CDE对E-51有显著的稀释增韧作用;随着CDE含量的增加,固化树脂的玻璃化转变温度逐渐降低;当CDE的加入量为20%时,固化物的冲击强度及拉伸强度达到最大值,分别为19.17 kJ/m2和56.81 MPa,弯曲强度为108.8 MPa。
以天然腰果酚為原料製備瞭一種高活性腰果酚基環氧稀釋劑(CDE),利用所製備的CDE與雙酚A型環氧樹脂( E-51)共混,再與甲基四氫苯酐進行交聯固化反應,通過力學性能測試,研究瞭稀釋劑含量對固化物性能的影響。實驗結果錶明:CDE對E-51有顯著的稀釋增韌作用;隨著CDE含量的增加,固化樹脂的玻璃化轉變溫度逐漸降低;噹CDE的加入量為20%時,固化物的遲擊彊度及拉伸彊度達到最大值,分彆為19.17 kJ/m2和56.81 MPa,彎麯彊度為108.8 MPa。
이천연요과분위원료제비료일충고활성요과분기배양희석제(CDE),이용소제비적CDE여쌍분A형배양수지( E-51)공혼,재여갑기사경분항진행교련고화반응,통과역학성능측시,연구료희석제함량대고화물성능적영향。실험결과표명:CDE대E-51유현저적희석증인작용;수착CDE함량적증가,고화수지적파리화전변온도축점강저;당CDE적가입량위20%시,고화물적충격강도급랍신강도체도최대치,분별위19.17 kJ/m2화56.81 MPa,만곡강도위108.8 MPa。
A cardanol-based epoxy ( CDE) diluents with high diluting and toughening properties was synthesized from cardanol. The blends of the prepared CDE and bisphenol type epoxy resin (E-51) at different mass ratios were cured with anhydride. The influence of the CDE content on the thermodynamic properties and mechanical properties of the cured epoxy was systematically investigated. The results showed that CDE had high diluting and toughening properties to E-51. The glass transition temperature (Tg) of cured epoxy decreased gradually with the increase of the content of CDE. When the CDE content was 20%,the impact strength and tensile strength of cured epoxy reached the maximum values (19. 17 kJ/m2 and 56. 81 MPa,respectively) while the high bending strength was 108. 8 MPa.