CAJ | 학술논문

针对电解液中酸锌离子浓度离线化验存在大滞后，难以实现锌电解过程在线优化控制的问题，研究了锌电解全流程酸锌离子浓度在线预测模型。在分析锌电解过程电化学反应机理的基础上，结合锌电解过程物料平衡，建立了锌电解动态反应模型。基于锌电解工业现场数据，采用 FCM 算法对锌电解工况进行分类，并辨识了不同工况条件下预测模型的参数，利用多工况模糊匹配实现了全流程酸锌离子的预测。工业数据验证结果表明所建模型能有效地反映酸锌离子浓度的变化趋势，为锌电解过程的优化控制奠定了基础。
침대전해액중산자리자농도리선화험존재대체후，난이실현자전해과정재선우화공제적문제，연구료자전해전류정산자리자농도재선예측모형。재분석자전해과정전화학반응궤리적기출상，결합자전해과정물료평형，건립료자전해동태반응모형。기우자전해공업현장수거，채용 FCM 산법대자전해공황진행분류，병변식료불동공황조건하예측모형적삼수，이용다공황모호필배실현료전류정산자리자적예측。공업수거험증결과표명소건모형능유효지반영산자리자농도적변화추세，위자전해과정적우화공제전정료기출。
The concentrations of zinc ion and sulfuric acid in electrolytic solution are detected by off-line analysis with large time-delay, which will be detrimental to the on-line optimal control for zinc electrowinning process (ZEWP). It is very significant to predict the concentrations of zinc ion and sulfuric acid on line. The electrochemical reaction mechanism for ZEWP is analyzed, and a dynamic model for ZEWP is established based on the material balance and electrochemical equations. Based on the data collected from the practical ZEWP, the working conditions of the ZEWP are classified using FCM algorithm. The parameters of the dynamic model under different classes are identified, and the concentrations of zinc ion and sulfuric acid in ZEWP are predicted using the multi-condition fuzzy matching approach. The results obtained from the practical data show that the model can effectively predict the variation tendency of the concentrations of zinc ion and sulfuric acid, which is profitable to the optimal control for ZEWP.